(betaS)-beta-Azido-4-chlorobenzeneethanol

Base Information

Chemical Name:(betaS)-beta-Azido-4-chlorobenzeneethanol
CAS No.:169272-17-7
Molecular Formula:C₈H₈ClN₃O
Molecular Weight:197.624
Hs Code.:
DSSTox Substance ID:DTXSID101293320

Synonyms:(betaS)-beta-Azido-4-chlorobenzeneethanol;DTXSID101293320;169272-17-7

Suppliers and Price of (betaS)-beta-Azido-4-chlorobenzeneethanol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (betaS)-beta-Azido-4-chlorobenzeneethanol

Chemical Property:

XLogP3:2.8
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:3
Rotatable Bond Count:3
Exact Mass:197.0355896
Heavy Atom Count:13
Complexity:198

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC(=CC=C1C(CO)N=[N+]=[N-])Cl
Isomeric SMILES:C1=CC(=CC=C1[C@@H](CO)N=[N+]=[N-])Cl

Technology Process of (betaS)-beta-Azido-4-chlorobenzeneethanol

There total 3 articles about (betaS)-beta-Azido-4-chlorobenzeneethanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 191109-44-1
(R)-4-(p-chlorophenyl)-1,3-dioxolane-2-one

: 169272-17-7
(S)-2-azido-2-(4-chlorophenyl)ethanol

Guidance literature:: With sodium azide; water; In N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(97)00322-0

Reference yield:

: 1073-67-2,24991-47-7
4-vinylbenzyl chloride

: 169272-17-7
(S)-2-azido-2-(4-chlorophenyl)ethanol

Guidance literature:: Multi-step reaction with 3 steps

1: K₃Fe(CN)6, K₂CO₃, (DHQD)2-PHAL, K₂OsO₄(H₂O)2

2: NaOH

3: NaN₃, H₂O / dimethylformamide

With sodium hydroxide; potassium osmate(VI); sodium azide; water; potassium carbonate; 1,4-bis(9-O-dihydroquinidine)phthalazine; potassium hexacyanoferrate(III); In N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(97)00322-0

Reference yield:

: 152142-03-5
(1R)-1-(4-chlorophenyl)-1,2-ethanediol

: 169272-17-7
(S)-2-azido-2-(4-chlorophenyl)ethanol

Guidance literature:: Multi-step reaction with 2 steps

1: NaOH

2: NaN₃, H₂O / dimethylformamide

With sodium hydroxide; sodium azide; water; In N,N-dimethyl-formamide;
DOI:10.1016/S0040-4020(97)00322-0