Technology Process of C46H74O9SSi
There total 9 articles about C46H74O9SSi which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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Multi-step reaction with 3 steps
1: 89 percent / 2,6-lutidine / CH2Cl2 / 2 h / 0 °C
2: NaIO4 / methanol; H2O / 48 h / 20 °C
3: 1.) LiNEt2 / tetrahydrofuran / 1.) -60 deg C, 15 min; 2.) -60 deg C to 25 deg C, 35 min
With
2,6-dimethylpyridine; sodium periodate; lithium diethylamide;
In
tetrahydrofuran; methanol; dichloromethane; water;
DOI:10.1016/S0040-4039(98)00691-1
- Guidance literature:
-
Multi-step reaction with 2 steps
1: 98 percent / 1.) O3; 2.) Me2S / CH2Cl2; methanol / 1.) -78 deg C; 2.) 0 deg C to 20 deg C, 10 h
2: 1.) LiNEt2 / tetrahydrofuran / 1.) -60 deg C, 15 min; 2.) -60 deg C to 25 deg C, 35 min
With
dimethylsulfide; lithium diethylamide; ozone;
In
tetrahydrofuran; methanol; dichloromethane;
DOI:10.1016/S0040-4039(98)00691-1
- Guidance literature:
-
Multi-step reaction with 4 steps
1: 81 percent / Sn(OTf)2, Et3N / CH2Cl2 / 1 h / -78 °C
2: 1.) Bu2BOMe, LiBH4; 2.) PPTS / 1.) THF; 2.) CH2Cl2, 18 h
3: 98 percent / 1.) O3; 2.) Me2S / CH2Cl2; methanol / 1.) -78 deg C; 2.) 0 deg C to 20 deg C, 10 h
4: 1.) LiNEt2 / tetrahydrofuran / 1.) -60 deg C, 15 min; 2.) -60 deg C to 25 deg C, 35 min
With
lithium borohydride; tin(II) trifluoromethanesulfonate; dimethylsulfide; dibutylborinic acid methyl ester; lithium diethylamide; pyridinium p-toluenesulfonate; ozone; triethylamine;
In
tetrahydrofuran; methanol; dichloromethane;
DOI:10.1016/S0040-4039(98)00691-1
