Pd(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)Cl₂

Base Information

• Chemical Name: Pd(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)Cl₂
• CAS No.: 214557-72-9
• Molecular Formula: C₂₆H₂₀Cl₂N₂Pd
• Molecular Weight: 537.784
• Mol file: 214557-72-9.mol

Synonyms:

Chemical Property of Pd(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)Cl₂

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of Pd(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)Cl₂

There total 1 articles about Pd(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)Cl₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) + Bathocuproine (4733-39-5) → Pd(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)Cl2 (214557-72-9)

Guidance literature:

In chloroform; ligand was added to stirring soln. Pd complex in CHCl3, mixt. was stirred for 20 h; soln. was filtered through Celite, filtrate was concd., Et2O was added, ppt. was collected by filtration, washed with Et2O, dried in air;

DOI:10.1021/ic800986t

Reference yield: 70.0%

Pd(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)Cl2 (214557-72-9) + carbon monoxide (201230-82-2) + Bathocuproine (4733-39-5) + sodium methylate (124-41-4) → Pd(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)(methoxycarbonyl)2 (214557-67-2)

Guidance literature:

In methanol; byproducts: NaCl; Ar-atmosphere; addn. of excess NaOMe and phenanthroline derivative to Pd-complex suspn., stirring (CO-stream, room temp., 20 h); distn. off of solvent, addn. of CH2Cl2, filtration off of NaCl (celite),evapn. (reduced pressure), drying (vac.); elem. anal.;

DOI:10.1016/S0022-328X(98)00742-6

Reference yield: 20.0%

Pd(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)Cl2 (214557-72-9) + carbon monoxide (201230-82-2) + Bathocuproine (4733-39-5) + potassium carbonate (584-08-7) → Pd(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)(methoxycarbonyl)2 (214557-67-2)

Guidance literature:

In methanol; Ar-atmosphere; addn. of excess K2CO3 to Pd-complex suspn. with phenanthroline derivative, stirring (CO-stream, room temp., 20 h); distn. off of solvent, addn. of CH2Cl2, filtration (celite), evapn. (reduced pressure), drying (vac.);

DOI:10.1016/S0022-328X(98)00742-6

upstream raw materials:

bis(benzonitrile)palladium(II) dichloride

Bathocuproine

Downstream raw materials:

Pd(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)(methoxycarbonyl)2