HMo(N[t-Bu]-3,5-C₆H₃Me₂)3

Base Information

• Chemical Name: HMo(N[t-Bu]-3,5-C₆H₃Me₂)3
• CAS No.: 1071139-06-4
• Molecular Formula: C₃₆H₅₅MoN₃
• Molecular Weight: 625.793
• Mol file: 1071139-06-4.mol

Synonyms:

Chemical Property of HMo(N[t-Bu]-3,5-C₆H₃Me₂)3

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of HMo(N[t-Bu]-3,5-C₆H₃Me₂)3

There total 6 articles about HMo(N[t-Bu]-3,5-C₆H₃Me₂)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

Mo(N[((t)Bu)(3,5-C6H3Me2)])3 + dibutylstannane (1002-53-5) → HMo(N[t-Bu]-3,5-C6H3Me2)3 (1071139-06-4)

Guidance literature:

In diethyl ether; under inert atm. soln. H2SnBu2 in Et2O was added dropwise to soln. Mo complex in Et2O and stirred at 20°C for 1 h; soln. was filtered through Celite, volatiles were removed, residue was extd. with n-pentane and stored at -35°C;

DOI:10.1021/ic800945m

Reference yield: 92.0%

Mo(N[((t)Bu)(3,5-C6H3Me2)])3 + diphenyltin (1011-95-6) → HMo(N[t-Bu]-3,5-C6H3Me2)3 (1071139-06-4)

Guidance literature:

In diethyl ether; under inert atm. soln. H2SnPh2 in Et2O was added dropwise to soln. Mo complex in Et2O and stirred at 20°C for 1 h; soln. was filtered through Celite, volatiles were removed, residue was extd. with n-pentane and stored at -35°C;

DOI:10.1021/ic800945m

Reference yield: 78.0%

hydrido(tricarbonyl)(cyclopentadienyl)molybdenum (12176-06-6) + Mo(N[((t)Bu)(3,5-C6H3Me2)])3 → dimer of (η(5)-cyclopentadienyl)tricarbonylmolybdenum + HMo(N[t-Bu]-3,5-C6H3Me2)3 (1071139-06-4)

Guidance literature:

In pentane; under inert atm. soln. Mo complexes in n-pentane was stirred at 20°C for 2 h; soln. was filtered, volatiles were removed in vacuo; elem. anal.;

DOI:10.1021/ic800945m

upstream raw materials:

dibutylstannane

diphenyltin

hydrido(tricarbonyl)(cyclopentadienyl)molybdenum

hydrogen

Refernces