Ru2(CO)6(μ-SCH2CH2CH2S)

Base Information

• Chemical Name: Ru2(CO)6(μ-SCH2CH2CH2S)
• CAS No.: 288141-53-7
• Molecular Formula: C₉H₆O₆Ru₂S₂
• Molecular Weight: 476.415
• Mol file: 288141-53-7.mol

Synonyms:

Chemical Property of Ru2(CO)6(μ-SCH2CH2CH2S)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ru2(CO)6(μ-SCH2CH2CH2S)

There total 1 articles about Ru2(CO)6(μ-SCH2CH2CH2S) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 20.0%

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + (C6H5)3SnS(CH2)3SSn(C6H5)3 (56535-49-0) → trans-{((C6H5)3Sn)2Ru(CO)4} (17653-14-4) + Ru2(CO)6(μ-SCH2CH2CH2S) (288141-53-7)

Guidance literature:

In tetrahydrofuran; N2; Ru compd. (0.15 mmol) and Sn compd. (0.156 mmol) refluxed in THF for3 h; evapd., chromd. (SiO2, hexane/CH2Cl2=7/3), recrystd. (hexane/CH2Cl2, 4°C), elem. anal.;

DOI:10.1016/j.ica.2009.05.011

Reference yield: 92.0%

Ru2(CO)6(μ-SCH2CH2CH2S) (288141-53-7) + bis-diphenylphosphinomethane (2071-20-7) → [diruthenium(carbonyl)4(μ-dppm)(μ-pdt)]

Guidance literature:

In toluene; byproducts: CO; (N2); refluxing toluene soln. of ruthenium compd. and diphosphine deriv.for 2 h; cooling, evapn., washing with light petroleum ether, dissolving in CH2Cl2, layering with methanol, isolation of crystals, NMR and IR;

DOI:10.1021/om100894w

Reference yield: 44.0%

Ru2(CO)6(μ-SCH2CH2CH2S) (288141-53-7) + triphenylphosphine (603-35-0) → (CO)5Ru2(PPh3)(μ-SCH2CH2CH2S) (288141-56-0)

Guidance literature:

In hexane; under N2, Ru-complex:Ph3P molar ratio was 1:1, stirring at room temp. for 1 h; solvent was removed in vac., chromy. on silica gel, elution with hexane/CH2Cl2, recrystn.f rom hexane/CH2Cl2 at -20 °C, elem. anal.;

DOI:10.1016/S0277-5387(00)00353-3

upstream raw materials:

dodecacarbonyl-triangulo-triruthenium

(C₆H₅)3SnS(CH₂)3SSn(C₆H₅)3

Downstream raw materials:

(CO)5Ru2(PPh3)(μ-SCH2CH2CH2S)