17653-14-4Relevant academic research and scientific papers
Ruthenium-tin complexes from the reaction of HSnPh3 with Ru3(CO)10(NCMe)2 and their reactions with bis(tri-t-butylphosphine)platinum
Adams, Richard D.,Captain, Burjor,Trufan, Eszter
, p. 3593 - 3602 (2008)
The compounds Ru3(CO)9(SnPh3)2(NCMe)(μ-H)2 (1), Ru3(CO)10(SnPh3)2(μ-H)2 (2), Ru(CO)4(SnPh3)2 (3) and Ru(CO)4(SnPh3)(H) (4) were obtained from the reaction of Ru3(CO)10(NCMe)2 with HSnPh3 in hexane solvent. Compounds 1, 3 and the new compound Ru3(CO)7(SnPh3)3(NCMe)2(μ-H)3 (5) were obtained from reaction of Ru3(CO)10(NCMe)2 with HSnPh3 in a CH2Cl2 and MeCN solvent mixture. Compound 2 and the new compound Ru3(CO)9(SnPh3)3(μ-H)3 (6) were obtained from reactions of 1 and 5 with CO, respectively. Compounds 2 and 6 eliminated benzene when heated to yield Ru3(CO)10(μ-SnPh2)2 (7) and Ru3(CO)9(μ-SnPh2)3 (8) which contain bridging SnPh2 ligands. Compound 7 was found to react with Pt (PBu3t)2 to yield the bis-Pt (PBu3t) adduct, Pt2 Ru3 (CO)10 (PBu3t)2 (μ3 - SnPh2)2 (9) in 59% yield by the addition of Pt (PBu3t) groups to two of the Ru-Sn bonds to the bridging SnPh2 ligands. Fenske-Hall molecular orbital calculations were performed to provide an understanding of the metal-metal bonding in the clusters of 7 and 9. Compounds 1, 2, 5, 6, 7 and 9 were characterized structurally by single crystal X-ray diffraction analysis.
Sn-S and Ru-Ru bonds cleavage reactions between [Ph3SnS(CH2)3SSnPh3] and Ru3(CO)12: X-ray crystal structures of [Ph3SnS(CH2)3SSnPh3] and trans-[R
Ghosh, Shishir,Pervin, Rehana,Raha, Arun K.,Kabir, Shariff E.,Nicholson, Brian K.
, p. 4226 - 4230 (2010/01/31)
The organotin complex [Ph3SnS(CH2)3SSnPh3] (1) was synthesized by PdCl2 catalyzed reaction between Ph3SnCl and disodium-1,3-propanedithiolate which in turn was prepared from 1,2-propanedith
