Methyl (1'S,2'R)-(+)-2',3'-Bis(benzyloxymethyl)-3'-cyclohexenylacetate

Base Information

Chemical Name:Methyl (1'S,2'R)-(+)-2',3'-Bis(benzyloxymethyl)-3'-cyclohexenylacetate
CAS No.:151062-72-5
Molecular Formula:C₂₅H₃₀O₄
Molecular Weight:394.511
Hs Code.:

Synonyms:

Suppliers and Price of Methyl (1'S,2'R)-(+)-2',3'-Bis(benzyloxymethyl)-3'-cyclohexenylacetate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of Methyl (1'S,2'R)-(+)-2',3'-Bis(benzyloxymethyl)-3'-cyclohexenylacetate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of Methyl (1'S,2'R)-(+)-2',3'-Bis(benzyloxymethyl)-3'-cyclohexenylacetate

There total 8 articles about Methyl (1'S,2'R)-(+)-2',3'-Bis(benzyloxymethyl)-3'-cyclohexenylacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 151062-62-3
(1S,2R,6R,7S,9S)-(+)-9-Hydroxy-4-oxatricyclo<5.2.2.0^2,6>undecan-3-one

: 151062-72-5
Methyl (1'S,2'R)-(+)-2',3'-Bis(benzyloxymethyl)-3'-cyclohexenylacetate

Guidance literature:: Multi-step reaction with 7 steps

1: 98 percent / pyridinium p-toluenesulfonate / CH₂Cl₂ / 3 h / Ambient temperature

2: 98 percent / LiAlH₄ / tetrahydrofuran / 2.5 h / Ambient temperature

3: 1) NaH, 2) (nBu)4NI / 1) DMF, r.t., 1 h, 2) r.t., 4 h

4: 98 percent / p-toluenesulfonic acid monohydrate (p-TsOH) / methanol / 6 h / Ambient temperature

5: 82 percent / pyridinium dichromate / CH₂Cl₂ / 8 h / Ambient temperature

7: 4-(dimethylamine)pyridine (DMAP), trifluoromethanesulfonyl chloride (TfCl), / CH₂Cl₂ / 1) 0 deg C, 15 min, 2) r.t., 3 h

With dmap; lithium aluminium tetrahydride; dipyridinium dichromate; trifluoromethane sulfonyl chloride; pyridinium p-toluenesulfonate; tetra-(n-butyl)ammonium iodide; sodium hydride; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; dichloromethane;

Reference yield:

: (1S,2S,4S,5R,6R)-(+)-5,6-Bis(hydroxymethyl)-2-(tetrahydro-2H-pyran-2-yloxy)bicyclo<2.2.2>octane

: 151062-72-5
Methyl (1'S,2'R)-(+)-2',3'-Bis(benzyloxymethyl)-3'-cyclohexenylacetate

Guidance literature:: Multi-step reaction with 5 steps

1: 1) NaH, 2) (nBu)4NI / 1) DMF, r.t., 1 h, 2) r.t., 4 h

2: 98 percent / p-toluenesulfonic acid monohydrate (p-TsOH) / methanol / 6 h / Ambient temperature

3: 82 percent / pyridinium dichromate / CH₂Cl₂ / 8 h / Ambient temperature

5: 4-(dimethylamine)pyridine (DMAP), trifluoromethanesulfonyl chloride (TfCl), / CH₂Cl₂ / 1) 0 deg C, 15 min, 2) r.t., 3 h

With dmap; dipyridinium dichromate; trifluoromethane sulfonyl chloride; tetra-(n-butyl)ammonium iodide; sodium hydride; toluene-4-sulfonic acid; In methanol; dichloromethane;

Reference yield:

: (1S,2R,6S,7R,8R,9R)-(+)-9-Hydroxy-8-iodo-4-oxatricyclo<5.2.2.0^2,6>undec-3-one

: 151062-72-5
Methyl (1'S,2'R)-(+)-2',3'-Bis(benzyloxymethyl)-3'-cyclohexenylacetate

Guidance literature:: Multi-step reaction with 8 steps

1: 94 percent / (nBu)3SnH / ethanol / 3 h / Ambient temperature

2: 98 percent / pyridinium p-toluenesulfonate / CH₂Cl₂ / 3 h / Ambient temperature

3: 98 percent / LiAlH₄ / tetrahydrofuran / 2.5 h / Ambient temperature

4: 1) NaH, 2) (nBu)4NI / 1) DMF, r.t., 1 h, 2) r.t., 4 h

5: 98 percent / p-toluenesulfonic acid monohydrate (p-TsOH) / methanol / 6 h / Ambient temperature

6: 82 percent / pyridinium dichromate / CH₂Cl₂ / 8 h / Ambient temperature

8: 4-(dimethylamine)pyridine (DMAP), trifluoromethanesulfonyl chloride (TfCl), / CH₂Cl₂ / 1) 0 deg C, 15 min, 2) r.t., 3 h

With dmap; lithium aluminium tetrahydride; dipyridinium dichromate; trifluoromethane sulfonyl chloride; tri-n-butyl-tin hydride; pyridinium p-toluenesulfonate; tetra-(n-butyl)ammonium iodide; sodium hydride; toluene-4-sulfonic acid; In tetrahydrofuran; methanol; ethanol; dichloromethane;