4',6'-O-benzylidene-2',3',10-tri-O-benzyl-10-hydroxyloganin

Base Information

Chemical Name:4',6'-O-benzylidene-2',3',10-tri-O-benzyl-10-hydroxyloganin
CAS No.:78924-54-6
Molecular Formula:C₄₅H₄₈O₁₁
Molecular Weight:764.87
Hs Code.:

Synonyms:

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Chemical Property of 4',6'-O-benzylidene-2',3',10-tri-O-benzyl-10-hydroxyloganin

Chemical Property:

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Technology Process of 4',6'-O-benzylidene-2',3',10-tri-O-benzyl-10-hydroxyloganin

There total 29 articles about 4',6'-O-benzylidene-2',3',10-tri-O-benzyl-10-hydroxyloganin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

: 78924-53-5
4',6'-O-benzylidene-2',3',10-tri-O-benzyl-geniposide

: 78924-54-6,78964-42-8,78964-48-4,78964-50-8
4',6'-O-benzylidene-2',3',10-tri-O-benzyl-allo-10-hydroxyloganin

Guidance literature:: With diborane; In tetrahydrofuran;

Reference yield:

: 24512-63-8,27745-20-6
geniposide

: 78924-54-6,78964-42-8,78964-48-4,78964-50-8
4',6'-O-benzylidene-2',3',10-tri-O-benzyl-10-hydroxyloganin

Guidance literature:: Multi-step reaction with 9 steps

1: 26.26 g / ZnCl₂ / Ambient temperature

2: 1.) n-Bu₄NI, NaH/DMSO / 1.) benzene, 15 min; 2.) benzene, r.t., 25 h

3: 53 percent / B₂H₆ / tetrahydrofuran

4: 622 mg / Jones reagent / acetone

5: 73.6 mg / silica gel / benzene; diethyl ether

6: 630 mg / NaBH₄ / dioxane; H₂O / 1 h / Ambient temperature

7: 237 mg / pyridine

8: 79 percent / acetone / 24 h / Heating

9: 203 mg / NaOCH₃ / methanol / 0.5 h / Heating

With pyridine; sodium tetrahydroborate; jones reagent; sodium methylate; silica gel; tetra-(n-butyl)ammonium iodide; sodium hydride; dimethyl sulfoxide; zinc(II) chloride; diborane; In tetrahydrofuran; 1,4-dioxane; methanol; diethyl ether; water; acetone; benzene;

Reference yield:

: 100-39-0
benzyl bromide

: 78924-54-6,78964-42-8,78964-48-4,78964-50-8
4',6'-O-benzylidene-2',3',10-tri-O-benzyl-10-hydroxyloganin

Guidance literature:: Multi-step reaction with 8 steps

1: 1.) n-Bu₄NI, NaH/DMSO / 1.) benzene, 15 min; 2.) benzene, r.t., 25 h

2: 53 percent / B₂H₆ / tetrahydrofuran

3: 622 mg / Jones reagent / acetone

4: 73.6 mg / silica gel / benzene; diethyl ether

5: 630 mg / NaBH₄ / dioxane; H₂O / 1 h / Ambient temperature

6: 237 mg / pyridine

7: 79 percent / acetone / 24 h / Heating

8: 203 mg / NaOCH₃ / methanol / 0.5 h / Heating

With pyridine; sodium tetrahydroborate; jones reagent; sodium methylate; silica gel; tetra-(n-butyl)ammonium iodide; sodium hydride; dimethyl sulfoxide; diborane; In tetrahydrofuran; 1,4-dioxane; methanol; diethyl ether; water; acetone; benzene;