chlorotris(triphenylstibine)copper(I)

Base Information

• Chemical Name: chlorotris(triphenylstibine)copper(I)
• CAS No.: 21507-21-1
• Molecular Formula: C₅₄H₄₅ClCuSb₃
• Molecular Weight: 1158.2
• Mol file: 21507-21-1.mol

Synonyms:

Chemical Property of chlorotris(triphenylstibine)copper(I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chlorotris(triphenylstibine)copper(I)

There total 1 articles about chlorotris(triphenylstibine)copper(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

triphenylantimony (603-36-1) + copper(l) chloride → chlorotris(triphenylstibine)copper(I) (21507-21-1)

Guidance literature:

In methanol; acetonitrile; for 3h; Reflux;

DOI:10.1007/s11030-019-10014-z

Reference yield: 70.6%

chlorotris(triphenylstibine)copper(I) (21507-21-1) + N,N-dimethyl-N'-phenylthiourea (705-62-4) → [Cu(triphenylstibine)(N,N-dimethyl-N'-phenylthiourea)2Cl] (263237-03-2)

Guidance literature:

In benzene; byproducts: SbPh3; benzene soln. of Cu(I)-contg. compd. (1 mmol) was added to a benzene soln. of a ligand (2 mmol); constant stirring at room temp. for 5 h; the vol. of the react. mixt. was reduced and petroleum ether (60-80°C) was added stepwise with constant shaking; the complex was sepd. by centrifugation, washed with petroleum ether and dried in vac. over P4O10 for several hs; elem. anal.;

DOI:10.1080/00945710009351760

Reference yield: 65.4%

thiazolidine-2-thione (134469-06-0) + chlorotris(triphenylstibine)copper(I) (21507-21-1) → [Cu(triphenylstibine)(1,3-thiazolidine-2-thione)2Cl] (263237-09-8)

Guidance literature:

In benzene; byproducts: SbPh3; benzene soln. of Cu(I)-contg. compd. (1 mmol) was added to a benzene soln. of a ligand (2 mmol); constant stirring at room temp. for 8 h; vol. of react. mixt. was reduced and petroleum ether (60-80°C) was added stepwise with shaking; the complex was sepd. by centrifugation,washed with petroleum ether and dried in vac. over P4O10; elem. anal.;

DOI:10.1080/00945710009351760

upstream raw materials:

triphenylantimony

Downstream raw materials:

[Cu(triphenylstibine)(1,3-thiazolidine-2-thione)2Cl]

[Cu(triphenylstibine)(N,N-dimethyl-N'-phenylthiourea)2Cl]

[Cu(triphenylstibine)(N,N-dibutyl-N'-phenylthiourea)2Cl]