fac-(o-bis(diphenylphosphino)benzene)PtMe₃(NHSO₂-p-C₆H₄CH₃)

Base Information

• Chemical Name: fac-(o-bis(diphenylphosphino)benzene)PtMe₃(NHSO₂-p-C₆H₄CH₃)
• CAS No.: 950767-99-4
• Molecular Formula: C₄₀H₄₁NO₂P₂PtS
• Molecular Weight: 856.865
• Mol file: 950767-99-4.mol

Synonyms:

Chemical Property of fac-(o-bis(diphenylphosphino)benzene)PtMe₃(NHSO₂-p-C₆H₄CH₃)

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of fac-(o-bis(diphenylphosphino)benzene)PtMe₃(NHSO₂-p-C₆H₄CH₃)

There total 1 articles about fac-(o-bis(diphenylphosphino)benzene)PtMe₃(NHSO₂-p-C₆H₄CH₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

fac-(o-bis(diphenylphosphino)benzene)(hydroxo)trimethylplatinum(IV) (950768-01-1) + toluene-4-sulfonamide (70-55-3) → fac-(o-bis(diphenylphosphino)benzene)PtMe3(NHSO2-p-C6H4CH3) (950767-99-4)

Guidance literature:

In tetrahydrofuran; (under N2); Pt-complex and ligand dissolved in THF, stirred overnight, MgSO4 added, stirred for 10 min; filtered, solvent removed under vac., residue washed with cold Et2O, ppt. dried under vac. overnight, recrystd. from THF/pentane;

DOI:10.1021/ja069191h

Reference yield:

fac-(o-bis(diphenylphosphino)benzene)PtMe3(NHSO2-p-C6H4CH3) (950767-99-4) → (o-bis(diphenylphosphino)benzene)dimethylplatinum(II) + (o-bis(diphenylphosphino)benzene)PtMe(NHSO2-p-C6H4CH3) (950768-12-4)

Guidance literature:

In benzene-d6; benzene; byproducts: ethane, MeCNSO2(p-C6H4CH3); (under N2); Pt-complex mixed with trimethylmethane in benzene, benzene removed under vac., C6D6 vac. transferred, kept in liq. N2, heated at 100°C; quenched in cold H2O or ice water; monitored by NMR; Kinetics;

DOI:10.1021/ja069191h

Reference yield:

fac-(o-bis(diphenylphosphino)benzene)PtMe3(NHSO2-p-C6H4CH3) (950767-99-4) + [K-18-crown-6][(NHSO2-p-C6H4(CH203CH3)] (950768-04-4) → fac-(o-bis(diphenylphosphino)benzene)PtMe3(NHSO2-p-C6H4(CH2)3CH3) (950767-98-3)

Guidance literature:

In benzene-d6; byproducts: [K-18-crown-6][NHSO2-p-C6H4CH3]; (under N2); Pt-complex mixed with ligand in C6D6, heated at 85°C for 3 d; quenched in cold H2O or ice water; monitored by NMR;

DOI:10.1021/ja069191h

upstream raw materials:

fac-(o-bis(diphenylphosphino)benzene)(hydroxo)trimethylplatinum(IV)

toluene-4-sulfonamide

Downstream raw materials:

(o-bis(diphenylphosphino)benzene)PtMe(NHSO₂-p-C₆H₄CH₃)

fac-(o-bis(diphenylphosphino)benzene)PtMe₃(NHSO₂-p-C₆H₄(CH₂)3CH₃)