1,21,23,25-tetrahexyl-5,9,13,17-tetrakis(diethylamino)-2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3,2,λ³]dioxaphosphocino[5,4-i:5',4'-i']benzo[1,2-d:5,4-d']bis[1,3,2λ³]benzodioxaphosphocine

Base Information

• Chemical Name: 1,21,23,25-tetrahexyl-5,9,13,17-tetrakis(diethylamino)-2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3,2,λ³]dioxaphosphocino[5,4-i:5',4'-i']benzo[1,2-d:5,4-d']bis[1,3,2λ³]benzodioxaphosphocine
• CAS No.: 178491-63-9
• Molecular Formula: C₆₈H₁₀₄N₄O₈P₄
• Molecular Weight: 1229.49
• Mol file: 178491-63-9.mol

Synonyms:

Chemical Property of 1,21,23,25-tetrahexyl-5,9,13,17-tetrakis(diethylamino)-2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3,2,λ³]dioxaphosphocino[5,4-i:5',4'-i']benzo[1,2-d:5,4-d']bis[1,3,2λ³]benzodioxaphosphocine

Chemical Property:

Purity/Quality:

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Useful:

Technology Process of 1,21,23,25-tetrahexyl-5,9,13,17-tetrakis(diethylamino)-2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3,2,λ³]dioxaphosphocino[5,4-i:5',4'-i']benzo[1,2-d:5,4-d']bis[1,3,2λ³]benzodioxaphosphocine

There total 1 articles about 1,21,23,25-tetrahexyl-5,9,13,17-tetrakis(diethylamino)-2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3,2,λ³]dioxaphosphocino[5,4-i:5',4'-i']benzo[1,2-d:5,4-d']bis[1,3,2λ³]benzodioxaphosphocine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 13.0%

phenyl phosphorous tetraethyldiamide (14684-28-7) + tetrahexylcalix[4]resorcinarene (132958-38-4,132958-39-5,191743-62-1,129831-84-1) → diphenyl-N,N-diethylphosphoramidite (14747-96-7) + 1,21,23,25-tetrahexyl-5,9,13,17-tetrakis(diethylamino)-2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3,2,λ3]dioxaphosphocino[5,4-i:5',4'-i']benzo[1,2-d:5,4-d']bis[1,3,2λ3]benzodioxaphosphocine (178491-63-9)

Guidance literature:

In 1,4-dioxane; at 20 - 25 ℃; for 264h;

DOI:10.1016/S0040-4020(03)00111-X

Reference yield: 49.0%

Phenyl azide (622-37-7) + 1,21,23,25-tetrahexyl-5,9,13,17-tetrakis(diethylamino)-2,20:3,19-dimetheno-1H,21H,23H,25H-bis[1,3,2,λ3]dioxaphosphocino[5,4-i:5',4'-i']benzo[1,2-d:5,4-d']bis[1,3,2λ3]benzodioxaphosphocine (178491-63-9) → C86H119N7O8P4

Guidance literature:

In 1,4-dioxane; at 20 ℃; for 336h;

DOI:10.1080/10426500210220

upstream raw materials:

phenyl phosphorous tetraethyldiamide

tetrahexylcalix[4]resorcinarene