trans-(bis(8-quinolinyl)amide)OsCl(PPh₃)2

Base Information

Chemical Name:trans-(bis(8-quinolinyl)amide)OsCl(PPh₃)2
CAS No.:1091616-13-5
Molecular Formula:C₅₄H₄₂ClN₃OsP₂
Molecular Weight:1020.55
Hs Code.:

trans-(bis(8-quinolinyl)amide)OsCl(PPh<sub>3</sub>)2

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Chemical Property of trans-(bis(8-quinolinyl)amide)OsCl(PPh₃)2

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Technology Process of trans-(bis(8-quinolinyl)amide)OsCl(PPh₃)2

There total 2 articles about trans-(bis(8-quinolinyl)amide)OsCl(PPh₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: lithium bis(8-quinolinyl)amide

: OsCl₂(PPh₃)4

: 1091616-13-5,1092107-74-8
trans-(bis(8-quinolinyl)amide)OsCl(PPh₃)2

Guidance literature:: In toluene; under N2 atm. soln. Li salt ligand in toluene was added to soln. Os complex in toluene and heated to 65°C for 5 h; react. mixt. was cooled to room temp., solvent was removed in vacuo, residue was washed with EtOH, Et2O and petroleum ether and dried in vacuo; elem. anal.;
DOI:10.1021/ic801047s

Reference yield:

: 1091616-13-5,1092107-74-8
cis-(bis(8-quinolinyl)amide)OsCl(PPh₃)2

: 1091616-13-5,1092107-74-8
trans-(bis(8-quinolinyl)amide)OsCl(PPh₃)2

Guidance literature:: In benzene; crystn. by vapor diffusion petroleum ether into soln. in benzene;
DOI:10.1021/ic801047s

Reference yield: 90.0%

: 60969-19-9
thallium(I) hexafluorophosphate

: 1091616-13-5,1092107-74-8
trans-(bis(8-quinolinyl)amide)OsCl(PPh₃)2

: 201230-82-2
carbon monoxide

: 1091616-37-3
[trans-(bis(8-quinolinyl)amide)Os(CO)(PPh₃)2][PF₆]

Guidance literature:: In tetrahydrofuran; soln. TlPF6 in THF was added to soln. Os complex in THF and stirred under CO atm. for 5 h; volatiles were removed in vacuo, residue was washed with EtOH and Et2O and dried in vacuo; elem. anal.;
DOI:10.1021/ic801047s