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[Pd(trimethylsilyl)(C6H5)(N,N,N',N'-tetramethylethylenediamine)]

Base Information Edit
  • Chemical Name:[Pd(trimethylsilyl)(C6H5)(N,N,N',N'-tetramethylethylenediamine)]
  • CAS No.:500227-74-7
  • Molecular Formula:C16H32N2PdSi
  • Molecular Weight:386.949
  • Hs Code.:
  • Mol file:500227-74-7.mol
[Pd(trimethylsilyl)(C<sub>6</sub>H<sub>5</sub>)(N,N,N',N'-tetramethylethylenediamine)]

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Suppliers and Price of [Pd(trimethylsilyl)(C6H5)(N,N,N',N'-tetramethylethylenediamine)]
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The product has achieved commercial mass production*data from LookChem market partment
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Chemical Property of [Pd(trimethylsilyl)(C6H5)(N,N,N',N'-tetramethylethylenediamine)] Edit
Chemical Property:
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Technology Process of [Pd(trimethylsilyl)(C6H5)(N,N,N',N'-tetramethylethylenediamine)]

There total 1 articles about [Pd(trimethylsilyl)(C6H5)(N,N,N',N'-tetramethylethylenediamine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:
Guidance literature:
In diethyl ether; byproducts: LiI; under Ar atm. using Schlenk techniques; suspn. of Pd-complex in Et2O cooled to -80°C; added to LiCH2SiMe3 precooled to -80°C; suspn. stirred for 0.5 h; slowly allowed to warm to -30°C; soln. warmed quickly o 0°C; H2O added at 0°C and stirred (few min); rapidly cooled to -40°C; org. layer sepd. by decantation; washed (Et2O); extracts dried (Na2SO4, 0°C); filtered (cottonwool/Celite); volatiles removed (vac.); recrystd. (acetone); elem. anal.;
DOI:10.1016/S0020-1693(02)00978-7
Guidance literature:
In acetone; byproducts: (CH3)2NCH2CH2N(CH3)2; under Ar atm. using Schlenk techniques; soln. of Pd-complex in acetone cooled to -40°C; mixed with soln. of 2,2'-bipyridine in acetone at-40°C; soln. warmed slowly to -10°C; soln. concd.; stored at -20°C over several ds; elem. anal.;
DOI:10.1016/S0020-1693(02)00978-7
upstream raw materials:

trimethylsilylmethyllithium

Downstream raw materials:

[Pd(CH2Si(CH3)3)(C6H5)(2,2'-bipyridine)]

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