PdMeI(Et2NC2H4PPh2-κ2-N,P)

Base Information

Chemical Name:PdMeI(Et2NC2H4PPh2-κ2-N,P)
CAS No.:956274-03-6
Molecular Formula:C₁₉H₂₇INPPd
Molecular Weight:533.728
Hs Code.:

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Chemical Property of PdMeI(Et2NC2H4PPh2-κ2-N,P)

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Technology Process of PdMeI(Et2NC2H4PPh2-κ2-N,P)

There total 1 articles about PdMeI(Et2NC2H4PPh2-κ2-N,P) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 46.0%

: 52522-40-4
tris(dibenzylideneacetone)dipalladium⁽⁰⁾ chloroform complex

: 2359-97-9
2-(diphenylphosphino)triethylamine

: 74-88-4
methyl iodide

: 956274-03-6
PdMeI(Et2NC2H4PPh2-κ2-N,P)

Guidance literature:: In benzene; under inert atm. to soln. Pd complex in benzene Et2NCH2CH2PPh2 and MeI were added and stirred at room temp. overnight; soln. was filtered through alumina, evapd. to dryness in vacuo, washed with hexane and recrystd. from CH2Cl2-hexane; elem. anal.;
DOI:10.1016/j.jorganchem.2007.04.029

Reference yield: 45.0%

: 14878-28-5
sodium tetracarbonyl cobaltate

: 956274-03-6
PdMeI(Et2NC2H4PPh2-κ2-N,P)

: (Et2NC2H4PPh2-κ2-N,P)MePd-Co(CO)4

Guidance literature:: In tetrahydrofuran; under inert atm. to soln. Pd complex in THF at -80°C soln. Co complex in THF was added, react. mixt. was stirred at -40°C for 3 h; volatiles were removed in vacuo, residue was extd. with toluene at -30°C, filtered and concd. in vacuo at -20°C, hexane was added,soln. was cooled to -30°C, ppt. was filtered, washed with hexane , dried in vacuo at r.t.; elem. anal.;
DOI:10.1016/j.jorganchem.2007.04.029

Reference yield: 15.0%

: 12107-35-6
Na[CpMo(CO)3]

: 956274-03-6
PdMeI(Et2NC2H4PPh2-κ2-N,P)

: [PdMoCp(CO)3(Et2NCH2CH2PPh2-κ1-P)]2

Guidance literature:: In tetrahydrofuran; under inert atm. to soln. Pd complex in THF at -80°C soln. Mo complex in THF was added, react. mixt. was stirred at -40°C for 3 h; volatiles were removed in vacuo, residue was extd. with benzene at -30°C, filtered and concd. in vacuo at -20°C, hexane was added,soln. was cooled to -30°C, ppt. was filtered, washed with hexane , dried in vacuo at r.t.;;
DOI:10.1016/j.jorganchem.2007.04.029