trans-bis(phenylamino)diiodoplatinum(II)

Base Information

Chemical Name:trans-bis(phenylamino)diiodoplatinum(II)
CAS No.:80373-46-2
Molecular Formula:C₁₂H₁₄I₂N₂Pt
Molecular Weight:635.146
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of trans-bis(phenylamino)diiodoplatinum(II)

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Technology Process of trans-bis(phenylamino)diiodoplatinum(II)

There total 7 articles about trans-bis(phenylamino)diiodoplatinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: potassium tetraiodoplatinate

: 62-53-3
aniline

: 80373-46-2,13878-37-0,6894-20-8
cis-bis(phenylamine)diiodoplatinum(II)

Guidance literature:: In ethanol; water; Pt complex in H2O reacted with large excess of amine in ethanol;
DOI:10.1016/j.ica.2006.07.098

Reference yield: 81.0%

: potassium tetraiodoplatinate

: 62-53-3
aniline

: 6894-20-8,80373-46-2,13878-37-0
trans-bis(phenylamino)diiodoplatinum(II)

Guidance literature:: In ethanol; water; amine in EtOH added to 0.2 equiv. of Pt complex in H2O, heated under stirring for several h, pptd.; ppt. filtered, washed (H2O, cold EtOH), dried (air, vac.);
DOI:10.1016/j.ica.2006.07.098

Reference yield:

: 80373-46-2,13878-37-0,6894-20-8
cis-bis(phenylamine)diiodoplatinum(II)

: 6894-20-8,80373-46-2,13878-37-0
trans-bis(phenylamino)diiodoplatinum(II)

Guidance literature:: With hydrogen iodide; aniline; In water; N,N-dimethyl-formamide; dissolved educt in min. volume of DMF, added excess of aniline and HI, warmed for few minutes then allowed to cool; pptd. by addn. of 1 M aq. NaI, filtered, washed with water, EtOH, ether, dried in vac. over silica gel;
DOI:10.1016/0022-2860(81)85263-5