(C₄F₉C₂H₄)2Sn(CH₂C₆H₅)2

Base Information

• Chemical Name: (C₄F₉C₂H₄)2Sn(CH₂C₆H₅)2
• CAS No.: 444809-28-3
• Molecular Formula: C₂₆H₂₂F₁₈Sn
• Molecular Weight: 795.142
• Mol file: 444809-28-3.mol

Synonyms:

Chemical Property of (C₄F₉C₂H₄)2Sn(CH₂C₆H₅)2

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₄F₉C₂H₄)2Sn(CH₂C₆H₅)2

There total 2 articles about (C₄F₉C₂H₄)2Sn(CH₂C₆H₅)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

1H,1H,2H,2H-perfluoro-n-hexyl bromide (38436-14-5) + dibenzyldibromotin(IV) (10113-32-3) → (C4F9C2H4)2Sn(CH2C6H5)2 (444809-28-3)

Guidance literature:

With Mg; In tetrahydrofuran; diethyl ether; (Ar); C4F9C2H4Br in Et2O was added dropwise to stirred suspn. of Mg in Et2O at 0°C; mixt. was stirred at room temp. for 3 h; dild. with Et2O; (C6H5CH2)2SnBr2 in THF was added at 0°C; mixt. was stirred at room temp. for 24 h; dild. with C6H14; filtered through celite pad; filtrate evapd.; residue chromd. (SiO2, C6H14);

DOI:10.1016/S0022-328X(01)01398-5

Reference yield:

benzyl bromide (100-39-0) → (C4F9C2H4)2Sn(CH2C6H5)2 (444809-28-3)

Guidance literature:

Multi-step reaction with 2 steps

1: water; toluene

2: Mg / tetrahydrofuran; diethyl ether

With Mg; In tetrahydrofuran; diethyl ether; water; toluene;

DOI:10.1016/S0022-328X(01)01398-5

upstream raw materials:

1H,1H,2H,2H-perfluoro-n-hexyl bromide

dibenzyldibromotin(IV)

benzyl bromide