(hydroperoxo)(phthalimido)bis(triphenylphosphino) platinum(II)

Base Information

• Chemical Name: (hydroperoxo)(phthalimido)bis(triphenylphosphino) platinum(II)
• CAS No.: 102982-53-6
• Molecular Formula: C₄₄H₃₅NO₄P₂Pt
• Molecular Weight: 898.794
• Mol file: 102982-53-6.mol

Synonyms:

Chemical Property of (hydroperoxo)(phthalimido)bis(triphenylphosphino) platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (hydroperoxo)(phthalimido)bis(triphenylphosphino) platinum(II)

There total 2 articles about (hydroperoxo)(phthalimido)bis(triphenylphosphino) platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

phthalimide (136918-14-4,85-41-6) + dioxygenbis(triphenylphosphine)platinum(0) (29894-57-3) → (hydroperoxo)(phthalimido)bis(triphenylphosphino) platinum(II) (102982-53-6)

Guidance literature:

In diethyl ether; N2-atmosphere; stirring (4 h, 0°C); filtration, washing (Et2O), drying (vac.); elem. anal.;

DOI:10.1016/0022-328X(85)80356-9

Reference yield: 37.0%

phthalimide (136918-14-4,85-41-6) + Pt((C6H5)3P)2(OC(CH3)2OO) (22455-21-6) → cis-diphthalimidobis(triphenylphosphine)platinum(II) (117306-60-2) + (hydroperoxo)(phthalimido)bis(triphenylphosphino) platinum(II) (102982-53-6)

Guidance literature:

In dichloromethane; The platinum complex and phthalimide were added to CH2Cl2 and the soln. stirred for 1 h or 24 h. Manipulations under N2.; evapn. to dryness in vacuo, IR; bis-succinimido complex is obtained only after 24 h stirring;

DOI:10.1016/S0020-1693(00)80218-2

Reference yield: 73.0%

(hydroperoxo)(phthalimido)bis(triphenylphosphino) platinum(II) (102982-53-6) + triphenylphosphine (603-35-0) → (hydroxo)(phthalimido)bis(triphenylphosphino) platinum(II) (131006-51-4)

Guidance literature:

In dichloromethane; byproducts: triphenylphosphine; To the soln. of the platinum complex PPh3 was added, the soln. was stirred for 4 h. Manipulations under N2.; evapn. to dryness, addn. of diethyl ether, filtn., washing with diethyl ether, recrystn. from CH2Cl2/diethyl ether, IR and thin-layer chromy. of the residue from evaporated diethyl ether washings, elem. anal.;

DOI:10.1016/S0020-1693(00)80218-2

upstream raw materials:

phthalimide

dioxygenbis(triphenylphosphine)platinum⁽⁰⁾

Pt((C₆H₅)3P)2(OC(CH₃)2OO)

Downstream raw materials:

(hydroxo)(phthalimido)bis(triphenylphosphino) platinum(II)

Refernces