trifluoromethanesulfonato(1,2,3-tris(2,6-dimethylphenylimino)butyl-κC(1),N(3))(2,6-dimethylphenylisocyanide)nickel

Base Information

• Chemical Name: trifluoromethanesulfonato(1,2,3-tris(2,6-dimethylphenylimino)butyl-κC(1),N(3))(2,6-dimethylphenylisocyanide)nickel
• CAS No.: 1204414-91-4
• Molecular Formula: C₃₈H₃₉F₃N₄NiO₃S
• Molecular Weight: 747.504
• Mol file: 1204414-91-4.mol

Synonyms:

Chemical Property of trifluoromethanesulfonato(1,2,3-tris(2,6-dimethylphenylimino)butyl-κC(1),N(3))(2,6-dimethylphenylisocyanide)nickel

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trifluoromethanesulfonato(1,2,3-tris(2,6-dimethylphenylimino)butyl-κC(1),N(3))(2,6-dimethylphenylisocyanide)nickel

There total 1 articles about trifluoromethanesulfonato(1,2,3-tris(2,6-dimethylphenylimino)butyl-κC(1),N(3))(2,6-dimethylphenylisocyanide)nickel which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

iodo(1,2,3-tris(2,6-dimethylphenylimino)butyl-κC(1),N(3))(2,6-dimethylphenylisocyanide)nickel + silver trifluoromethanesulfonate (2923-28-6) → trifluoromethanesulfonato(1,2,3-tris(2,6-dimethylphenylimino)butyl-κC(1),N(3))(2,6-dimethylphenylisocyanide)nickel (1204414-91-4)

Guidance literature:

In dichloromethane; under Ar, Schlenk technique; mixt. of Ni complex and Ag triflate in CH2Cl2 stirred at room temp. for 4 h (colour of soln. turned red); soln. filtered through Celite, filtrate concd. under vac., residue dissolved in toluene, soln. layered with hexane, crystals isolated; elem. anal.;

DOI:10.1016/j.poly.2009.09.007

Reference yield: 72.0%

trifluoromethanesulfonato(1,2,3-tris(2,6-dimethylphenylimino)butyl-κC(1),N(3))(2,6-dimethylphenylisocyanide)nickel (1204414-91-4) + lithium bromide (7550-35-8) → bromo(1,2,3-tris(2,6-dimethylphenylimino)butyl-κC(1),N(3))(2,6-dimethylphenylisocyanide)nickel (1204414-92-5)

Guidance literature:

In acetone; under Ar, Schlenk technique; mixt. of Ni complex and LiBr in acetone stirred at room temp. for 16 h; soln. filtered through Celite, filtrate concd. under vac., residue dissolved in CH2Cl2, soln. layered with hexane, crystals isolated; elem. anal.;

DOI:10.1016/j.poly.2009.09.007

Reference yield: 63.0%

trifluoromethanesulfonato(1,2,3-tris(2,6-dimethylphenylimino)butyl-κC(1),N(3))(2,6-dimethylphenylisocyanide)nickel (1204414-91-4) + lithium chloride → chloro(1,2,3-tris(2,6-dimethylphenylimino)butyl-κC(1),N(3))(2,6-dimethylphenylisocyanide)nickel (1204414-93-6)

Guidance literature:

In acetone; under Ar, Schlenk technique; mixt. of Ni complex and LiCl in acetone stirred at room temp. for 16 h; soln. filtered through Celite, filtrate concd. under vac., residue dissolved in CH2Cl2, soln. layered with hexane, crystals isolated; elem. anal.;

DOI:10.1016/j.poly.2009.09.007

upstream raw materials:

silver trifluoromethanesulfonate

Downstream raw materials:

((CH₃)2C₆H₃NC)Ni(CH₂Cl₂)(CN(C₆H₃(CH₃)2)CN(C₆H₃(CH₃)2)CCH₃N(C₆H₃(CH₃)2))⁽¹⁺⁾*CF₃SO₂O^(1-)=[NiC₃₈H₄₁N₄Cl₂]OSO₂CF₃

bromo(1,2,3-tris(2,6-dimethylphenylimino)butyl-κC(1),N(3))(2,6-dimethylphenylisocyanide)nickel

chloro(1,2,3-tris(2,6-dimethylphenylimino)butyl-κC(1),N(3))(2,6-dimethylphenylisocyanide)nickel

(bromo[1,2,3-tris(2,6-dimethylphenylimino)butyl](2,6-dimethylphenylisocyanide)nickel)(dibromo)zinc(II)