p-Bromoacetophenone oxime, (Z)-

Base Information

• Chemical Name: p-Bromoacetophenone oxime, (Z)-
• CAS No.: 73744-33-9
• Molecular Formula: C₈H₈BrNO
• Molecular Weight: 214.062
• UNII: O3128O579B
• DSSTox Substance ID: DTXSID60224063
• Nikkaji Number: J2.588.565A,J960.580K
• Wikidata: Q27258954
• Mol file: 73744-33-9.mol

Synonyms:p-Bromoacetophenone oxime, (Z)-;1-(4-Bromophenyl)ethanone oxime;73744-33-9;UNII-O3128O579B;Ethanone, 1-(4-bromophenyl)-, oxime, (Z)-;Ethanone, 1-(4-bromophenyl)-, oxime, (1Z)-;O3128O579B;(E)-1-(4-bromophenyl)ethan-1-one oxime;4'-Bromoacetophenone oxime;p-Bromoacetophenone oxime;(E)-p-bromoacetophenone oxime;4'-Bromoacetophenone (E)-oxime;DTXSID60224063;HMS1542O08;AKOS000491147;(1Z)-1-(4-bromophenyl)ethanone oxime;P-BROMOACETOPHENONE OXIME Z-FORM [MI];Q27258954

Chemical Property of p-Bromoacetophenone oxime, (Z)-

Chemical Property:

• XLogP3: 2.6
• Hydrogen Bond Donor Count: 1
• Hydrogen Bond Acceptor Count: 2
• Rotatable Bond Count: 1
• Exact Mass: 212.97893
• Heavy Atom Count: 11
• Complexity: 150

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: CC(=NO)C1=CC=C(C=C1)Br
• Isomeric SMILES: C/C(=N/O)/C1=CC=C(C=C1)Br

Technology Process of p-Bromoacetophenone oxime, (Z)-

There total 5 articles about p-Bromoacetophenone oxime, (Z)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

para-bromoacetophenone (99-90-1) → p-bromoacetophenone oxime (59862-55-4,73744-33-9,5798-71-0)

Guidance literature:

With hydroxylamine;

DOI:10.1016/j.tetlet.2006.06.135

Reference yield: 82.0%

1-bromo-4-ethenyl-benzene (2039-82-9) → p-bromoacetophenone oxime (59862-55-4,73744-33-9,5798-71-0)

Guidance literature:

With sodium tetrahydroborate; tert.-butylnitrite; iron(II) phthalocyanine; hydrogen; In ethanol; at 20 ℃; for 3h; under 7500.75 Torr;

DOI:10.1039/b900326f

Reference yield:

para-bromoacetophenone (99-90-1) → p-bromoacetophenone oxime (59862-55-4,73744-33-9,5798-71-0) + 4-bromoacetanilide (103-88-8)

Guidance literature:

With hydroxylamine hydrochloride; trifluoroacetic acid; at 70 ℃; for 16h; Inert atmosphere;

DOI:10.1016/j.catcom.2014.02.007

upstream raw materials:

para-bromoacetophenone

1-(4-Bromo-phenyl)-1-hydroxyamino-ethanol

1-bromo-4-ethenyl-benzene

Downstream raw materials:

1-(4-bromophenyl)ethylamine

N-(4-bromophenyl)thioacetamide

3-(4-bromophenyl)isoxazolon-5(4H)-one

C₁₆H₁₂BrF₃N₂O₂