PhBi(2,6-C₅H₃N(CEt₂O)2)

Base Information

• Chemical Name: PhBi(2,6-C₅H₃N(CEt₂O)2)
• CAS No.: 255870-71-4
• Molecular Formula: C₂₁H₂₈BiNO₂
• Molecular Weight: 535.439
• Mol file: 255870-71-4.mol

Synonyms:

Chemical Property of PhBi(2,6-C₅H₃N(CEt₂O)2)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of PhBi(2,6-C₅H₃N(CEt₂O)2)

There total 1 articles about PhBi(2,6-C₅H₃N(CEt₂O)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

2,6-pyridinebis(diethylmethanol) (101086-42-4) + sodium ethanolate (141-52-6) + dibromophenylbismuthane (39110-02-6) → PhBi(2,6-C5H3N(CEt2O)2) (255870-71-4)

Guidance literature:

In ethanol; all operations under N2; ethanolic soln. of NaOEt added to soln. of Bi compd. at -30°C, mixt. warmed gradually to -15°C within 1 h; soln. of org. compd. added at -30°C, mixt. warmed to room temp.within 5 h; EtOH removed in vac., CH2Cl2 added, filtered, filtrate evapd. in vac., purifd. from unreacted comds., product washed with THF, dried in vac., recrystd. from 1,2-dichloroethane/hexane; elem. anal.;

DOI:10.1021/om990683v

upstream raw materials:

2,6-pyridinebis(diethylmethanol)

sodium ethanolate

dibromophenylbismuthane