methyl NP-di-p-anisylphosphonamidate

Base Information

• Chemical Name: methyl NP-di-p-anisylphosphonamidate
• CAS No.: 83470-37-5
• Molecular Formula: C₁₅H₁₈NO₄P
• Molecular Weight: 307.286
• Mol file: 83470-37-5.mol

Synonyms:

Chemical Property of methyl NP-di-p-anisylphosphonamidate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of methyl NP-di-p-anisylphosphonamidate

There total 3 articles about methyl NP-di-p-anisylphosphonamidate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

di-p-anisylphosphinic azide (83470-25-1) → P,P-bis(4-methoxyphenyl)phosphinic amide (83470-32-0) + methyl bis(4-methoxyphenyl)phosphinate (83470-31-9) + methyl NP-di-p-anisylphosphonamidate (83470-37-5)

Guidance literature:

In methanol; at 10 ℃; for 3.3h; Irradiation;

DOI:10.1016/0040-4020(82)80240-8

Reference yield:

bis(4-methoxyphenyl)phosphinic acid (20434-05-3) → methyl NP-di-p-anisylphosphonamidate (83470-37-5)

Guidance literature:

Multi-step reaction with 3 steps

1: SOCl₂ / 2 h / Heating

2: 48 percent / sodium azide / acetonitrile / 16 h / Ambient temperature

3: 53 percent / 3.3 h / 10 °C / Irradiation

With thionyl chloride; sodium azide; In acetonitrile;

DOI:10.1016/0040-4020(82)80240-8

Reference yield:

bis(4-methoxyphenyl)phosphinic acid chloride (20434-06-4) → methyl NP-di-p-anisylphosphonamidate (83470-37-5)

Guidance literature:

Multi-step reaction with 2 steps

1: 48 percent / sodium azide / acetonitrile / 16 h / Ambient temperature

2: 53 percent / 3.3 h / 10 °C / Irradiation

With sodium azide; In acetonitrile;

DOI:10.1016/0040-4020(82)80240-8

upstream raw materials:

di-p-anisylphosphinic azide

bis(4-methoxyphenyl)phosphinic acid

bis(4-methoxyphenyl)phosphinic acid chloride