OsClH(P(C₆H₅)3)((C₆H₅)2PCH₂CH₂CHCHCH₂CH₂P(C₆H₅)2)

Base Information

• Chemical Name: OsClH(P(C₆H₅)3)((C₆H₅)2PCH₂CH₂CHCHCH₂CH₂P(C₆H₅)2)
• CAS No.: 474082-75-2
• Molecular Formula: C₄₈H₄₆ClOsP₃
• Molecular Weight: 941.468
• Mol file: 474082-75-2.mol

Synonyms:

Chemical Property of OsClH(P(C₆H₅)3)((C₆H₅)2PCH₂CH₂CHCHCH₂CH₂P(C₆H₅)2)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of OsClH(P(C₆H₅)3)((C₆H₅)2PCH₂CH₂CHCHCH₂CH₂P(C₆H₅)2)

There total 1 articles about OsClH(P(C₆H₅)3)((C₆H₅)2PCH₂CH₂CHCHCH₂CH₂P(C₆H₅)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

[OsH3Cl(P(C6H5)3)3] + 1,6-bis(diphenylphosphino)-trans-hex-3-ene (64730-60-5) → OsClH(P(C6H5)3)((C6H5)2PCH2CH2CHCHCH2CH2P(C6H5)2) (474082-75-2)

Guidance literature:

In benzene; under N2, room temp., stirring for 5 h; soln. vol. was reduced in vac., hexane was added, solid was filtered off, washed 3 times with hexane, dried in vac., elem. anal.;

DOI:10.1002/1099-0682(200207)2002:7<1697::AID-EJIC1697>3.0.CO;2-O

Reference yield: 52.0%

sodium tetrahydroborate (16940-66-2) + OsClH(P(C6H5)3)((C6H5)2PCH2CH2CHCHCH2CH2P(C6H5)2) (474082-75-2) + water (7732-18-5) → trans-[OsH2(PPh3)(Ph2PCH2CH2CHCHCH2CH2PPh2)*3H2O

Guidance literature:

In ethanol; under N2, 10 equiv. of NaBH4, stirring at room temp. for 30 min; solvent was removed in vac., residue was extd. with C6H6, soln. vol. wasreduced, hexane was added, solid was filtered off, washed 3 times with hexane, dried in vac., elem. anal.;

DOI:10.1002/1099-0682(200207)2002:7<1697::AID-EJIC1697>3.0.CO;2-O

Reference yield:

OsClH(P(C6H5)3)((C6H5)2PCH2CH2CHCHCH2CH2P(C6H5)2) (474082-75-2) + hydrogen (1333-74-0) + thallium(I) triflate (73491-36-8) → OsH(H2)(P(C6H5)3)((C6H5)2PCH2CH2CHCHCH2CH2P(C6H5)2)(1+)*CF3SO3(1-)=OsH(H2)(((C6H5)2PCH2CH2CH)2)(P(C6H5)3)CF3SO3 (474082-81-0)

Guidance literature:

In dichloromethane-d2; room temp., 3 equiv. of TlO3SCF3 was added, storage for 5 h under H2; detected by (1)H, (13)C and (31)P NMR;

DOI:10.1002/1099-0682(200207)2002:7<1697::AID-EJIC1697>3.0.CO;2-O

upstream raw materials:

1,6-bis(diphenylphosphino)-trans-hex-3-ene

Downstream raw materials:

OsH(H₂)(P(C₆H₅)3)((C₆H₅)2PCH₂CH₂CHCHCH₂CH₂P(C₆H₅)2)⁽¹⁺⁾*CF₃SO₃^(1-)=OsH(H₂)(((C₆H₅)2PCH₂CH₂CH)2)(P(C₆H₅)3)CF₃SO₃