1-Cyclohexene-1-methanol, 6,6-dimethyl-2-(trifluoromethyl)-

Base Information

Chemical Name:1-Cyclohexene-1-methanol, 6,6-dimethyl-2-(trifluoromethyl)-
CAS No.:105986-26-3
Molecular Formula:C10H15F3O
Molecular Weight:208.224
Hs Code.:

Synonyms:

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Chemical Property of 1-Cyclohexene-1-methanol, 6,6-dimethyl-2-(trifluoromethyl)-

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
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MSDS Files:: SDS file from LookChem

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Technology Process of 1-Cyclohexene-1-methanol, 6,6-dimethyl-2-(trifluoromethyl)-

There total 13 articles about 1-Cyclohexene-1-methanol, 6,6-dimethyl-2-(trifluoromethyl)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 105986-25-2
6,6-Dimethyl-2-trifluoromethyl-cyclohex-1-enecarboxylic acid ethyl ester

: 105986-26-3
(6,6-Dimethyl-2-trifluoromethyl-cyclohex-1-enyl)-methanol

Guidance literature:: With diisobutylaluminium hydride; In hexane; at -78 ℃; for 24h;
DOI:10.1016/S0040-4039(00)95054-8

Reference yield:

: 1,1,1-Trifluoro-5-(tetrahydro-pyran-2-yloxy)-pent-3-yn-2-ol

: 105986-26-3
(6,6-Dimethyl-2-trifluoromethyl-cyclohex-1-enyl)-methanol

Guidance literature:: Multi-step reaction with 9 steps

1: hydrogen / PtO₂ / methanol

2: 2,6-lutidune / CH₂Cl₂

3: 85 percent / p-TsOH / methanol

4: LiBr / acetone

5: 1.) Mg 2.) 3P>4 / THF

6: n-BuF₄ / tetrahydrofuran

7: Na₂Cr₂O₇*2H₂O, H₂SO₄ / acetic acid / Ambient temperature

8: 78 percent / LiH / tetrahydrofuran; hexamethylphosphoric acid triamide / 48 h / Heating

9: 73 percent / DIBAL-H / hexane / 24 h / -78 °C

With 2,6-dimethylpyridine; sodium dichromate; tetrakiscopper(I); sulfuric acid; hydrogen; lithium hydride; diisobutylaluminium hydride; toluene-4-sulfonic acid; magnesium; lithium bromide; platinum(IV) oxide; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane; dichloromethane; acetic acid; acetone;
DOI:10.1016/S0040-4039(00)95054-8

Reference yield:

: 245069-30-1
1,1,1-trifluoro-5-[(tetrahydro-2H-pyran-2-yl)oxy]-3-pentyn-2-one

: 105986-26-3
(6,6-Dimethyl-2-trifluoromethyl-cyclohex-1-enyl)-methanol

Guidance literature:: Multi-step reaction with 10 steps

1: 90.3 percent / NaBH₄ / ethanol

2: hydrogen / PtO₂ / methanol

3: 2,6-lutidune / CH₂Cl₂

4: 85 percent / p-TsOH / methanol

5: LiBr / acetone

6: 1.) Mg 2.) 3P>4 / THF

7: n-BuF₄ / tetrahydrofuran

8: Na₂Cr₂O₇*2H₂O, H₂SO₄ / acetic acid / Ambient temperature

9: 78 percent / LiH / tetrahydrofuran; hexamethylphosphoric acid triamide / 48 h / Heating

10: 73 percent / DIBAL-H / hexane / 24 h / -78 °C

With 2,6-dimethylpyridine; sodium tetrahydroborate; sodium dichromate; tetrakiscopper(I); sulfuric acid; hydrogen; lithium hydride; diisobutylaluminium hydride; toluene-4-sulfonic acid; magnesium; lithium bromide; platinum(IV) oxide; In tetrahydrofuran; methanol; N,N,N,N,N,N-hexamethylphosphoric triamide; ethanol; hexane; dichloromethane; acetic acid; acetone;
DOI:10.1016/S0040-4039(00)95054-8