[(Au(phenylthiolato))2(4,4'-Ph₂PC₆H₄C₆H₄PPh₂)]

Base Information

• Chemical Name: [(Au(phenylthiolato))2(4,4'-Ph₂PC₆H₄C₆H₄PPh₂)]
• CAS No.: 1315565-84-4
• Molecular Formula: C₄₈H₃₈Au₂P₂S₂
• Molecular Weight: 1134.84
• Mol file: 1315565-84-4.mol

Synonyms:

Chemical Property of [(Au(phenylthiolato))2(4,4'-Ph₂PC₆H₄C₆H₄PPh₂)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(Au(phenylthiolato))2(4,4'-Ph₂PC₆H₄C₆H₄PPh₂)]

There total 1 articles about [(Au(phenylthiolato))2(4,4'-Ph₂PC₆H₄C₆H₄PPh₂)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

4,4′-bis(diphenylphosphino)biphenylene (4129-44-6) + (phenylthiolate)gold(I) (1192-39-8) → [(Au(phenylthiolato))2(4,4'-Ph2PC6H4C6H4PPh2)] (1315565-84-4)

Guidance literature:

In dichloromethane; addn. of diphosphine deriv. to suspn. of gold compd. in CH2Cl2, stirringfor 1.5 in dark; passing through silica, evapn., recrystn. (CH2Cl2/benzene/heptane) at 5°C, collecting crystals, washing with pentane, drying in vac., elem. anal.;

DOI:10.1039/c1dt10437c

Reference yield: 75.0%

silver(I) hexafluorophosphate (26042-63-7) + (tetrahydrothiophene)gold(I) chloride (39929-21-0) + [(Au(phenylthiolato))2(4,4'-Ph2PC6H4C6H4PPh2)] (1315565-84-4) + 4,4′-bis(diphenylphosphino)biphenylene (4129-44-6) → [(Au2(phenylthiolato))2(4,4'-Ph2PC6H4C6H4PPh2)2](PF6)2

Guidance literature:

In dichloromethane; byproducts: AgCl; (N2); addn. of diphosphine deriv. to soln. of (tetrahydrothiophene)gold chloride in CH2Cl2, stirring for 10 min, addn. of soln. of silver compd., stirring for 30 min, filtration, addn. to soln. of digold compd. in CH2Cl2, stirring for 3 h in dark; filtration, evapn., repetitious recrystn. (CH2Cl2/acetone/heptane) at room temp., collecting crystals, washing with diethyl ether, drying in vac., elem. anal.;

DOI:10.1039/c1dt10437c

Reference yield:

ferrocenium hexafluorophosphate + [(Au(phenylthiolato))2(4,4'-Ph2PC6H4C6H4PPh2)] (1315565-84-4) → [(Au2(phenylthiolato))2(4,4'-Ph2PC6H4C6H4PPh2)2](PF6)2

Guidance literature:

In not given; byproducts: Fe(C5H5)2; treatment of gold compd. with ferrocenium salt;

DOI:10.1039/c1dt10437c

upstream raw materials:

4,4′-bis(diphenylphosphino)biphenylene

(phenylthiolate)gold(I)