[Pd(η2-(S,S')-(Z,E-2,2-diacetyl-1,1-ethylenedithiolato))(CNC6H3Me2-2,6)2]

Base Information

• Chemical Name: [Pd(η2-(S,S')-(Z,E-2,2-diacetyl-1,1-ethylenedithiolato))(CNC6H3Me2-2,6)2]
• CAS No.: 573925-76-5
• Molecular Formula: C₂₄H₂₄N₂O₂PdS₂
• Molecular Weight: 543.019
• Mol file: 573925-76-5.mol

Synonyms:

Chemical Property of [Pd(η2-(S,S')-(Z,E-2,2-diacetyl-1,1-ethylenedithiolato))(CNC6H3Me2-2,6)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pd(η2-(S,S')-(Z,E-2,2-diacetyl-1,1-ethylenedithiolato))(CNC6H3Me2-2,6)2]

There total 1 articles about [Pd(η2-(S,S')-(Z,E-2,2-diacetyl-1,1-ethylenedithiolato))(CNC6H3Me2-2,6)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

bis(benzonitrile)palladium(II) chloride (14220-64-5,39958-10-6,15617-18-2) + dithallium 2,2-diacetyl-1,1-ethylenedithiolate + 2,6-dimethylphenyl isonitrile (119072-54-7,2769-71-3) → [Pd(η2-(S,S')-(Z,E-2,2-diacetyl-1,1-ethylenedithiolato))(CNC6H3Me2-2,6)2] (573925-76-5)

Guidance literature:

In dichloromethane; byproducts: TlCl; to a suspn. of Tl-contg. compd. (ca. 0.4 mmol) in CH2Cl2 were added the equimolar amt. of Pd-contg. compd. and 2 equiv. of isocyanide; the mixt.was stirred for 3 h; the mixt. was filtered through Celite; the soln. was concd. and Et2O added to ppt. the solid; it was recrystd. from CH2Cl2 and Et2O and suction dried; elem. anal.;

DOI:10.1021/ic0343758

Reference yield: 94.0%

[Pd(η2-(S,S')-(Z,E-2,2-diacetyl-1,1-ethylenedithiolato))(CNC6H3Me2-2,6)2] (573925-76-5) + diethylamine (109-89-7) → [Pd(η2-(S,S')-(2,2-diacetyl-1,1-ethylenedithiolato))CN(C6H3Me2-2,6))(C(NEt2)(NH(C6H3Me2-2,6))]

Guidance literature:

In dichloromethane; to a soln. of Pd-contg. compd. (ca. 0.20 mmol) in CH2Cl2 was added the equimolar amt. of NHEt2; stirring for 15 h; the soln. was concd. and Et2O was added to ppt. a cream solid; the solidwas filtered, washed with Et2O, and suction dried; elem. anal.;

DOI:10.1021/ic0343758

Reference yield: 83.0%

[Pd(η2-(S,S')-(Z,E-2,2-diacetyl-1,1-ethylenedithiolato))(CNC6H3Me2-2,6)2] (573925-76-5) + ammonia (7664-41-7) → [Pd(η2-(S,S')-(2,2-diacetyl-1,1-ethylenedithiolato))(C(NH2)(NH(C6H3Me2-2,6)))2]

Guidance literature:

In tetrahydrofuran; NH3 was bubbled through a soln. of Pd-contg. compd. (0.51 mmol) in THF for 1 h; stirring for 15 h; the soln. was filtered and the solid washed with Et2O; elem. anal.;

DOI:10.1021/ic0343758

upstream raw materials:

bis(benzonitrile)palladium(II) chloride

2,6-dimethylphenyl isonitrile