P(C₆H₅)4⁽¹⁺⁾*Cd(SC(O)CH₃)3^(1-) = [P(C₆H₅)4][Cd(SC(O)CH₃)3]

Base Information

• Chemical Name: P(C₆H₅)4⁽¹⁺⁾*Cd(SC(O)CH₃)3^(1-) = [P(C₆H₅)4][Cd(SC(O)CH₃)3]
• CAS No.: 259672-98-5
• Molecular Formula: C₆H₉CdO₃S₃*C₂₄H₂₀P
• Molecular Weight: 677.14
• Mol file: 259672-98-5.mol

Synonyms:

Chemical Property of P(C₆H₅)4⁽¹⁺⁾*Cd(SC(O)CH₃)3^(1-) = [P(C₆H₅)4][Cd(SC(O)CH₃)3]

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of P(C₆H₅)4⁽¹⁺⁾*Cd(SC(O)CH₃)3^(1-) = [P(C₆H₅)4][Cd(SC(O)CH₃)3]

There total 1 articles about P(C₆H₅)4⁽¹⁺⁾*Cd(SC(O)CH₃)3^(1-) = [P(C₆H₅)4][Cd(SC(O)CH₃)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 53.0%

cadmium(II) chloride monohydrate + tetraphenyl phosphonium chloride (2001-45-8) + tiolacetic acid (507-09-5) → P(C6H5)4(1+)*Cd(SC(O)CH3)3(1-) = [P(C6H5)4][Cd(SC(O)CH3)3] (259672-98-5)

Guidance literature:

With Et₃N; In water; byproducts: [Et3NH]Cl; (N2); addn. of thioacetic acid to a stirred aq. soln. of NEt3, addn. of the Cd salt in H2O, stirring (10 min), addn. of (Ph4P)Cl in H2O, stirring (1 h); extn. (CH2Cl2), washing (deionised H2O), addn. of Et2O, crystn. after standing in a refrigerator overnight, decantation, washing (Et2O), drying (vac.); elem. anal.;

DOI:10.1039/a906494j

Reference yield: 84.0%

P(C6H5)4(1+)*Cd(SC(O)CH3)3(1-) = [P(C6H5)4][Cd(SC(O)CH3)3] (259672-98-5) + tetraphenyl phosphonium chloride (2001-45-8) → 2[(C6H5)4P](1+)*[Cd(SCOCH3)3Cl](2-)=[(C6H5)4P]2[Cd(SCOCH3)3Cl]

Guidance literature:

In dichloromethane; (N2); solid PH4PCl added to soln. of Cd complex in CH2Cl2; the mixt. stirred for 1 h; the ppt. filtered off, filtrate layered with ether and left at 0°C for 2 ds to give crystals; elem. anal.;

DOI:10.1016/S0020-1693(02)00731-4

upstream raw materials:

tetraphenyl phosphonium chloride

tiolacetic acid