(tri(3-methylphenyl)phosphine)gold thiocyanate

Base Information

Chemical Name:(tri(3-methylphenyl)phosphine)gold thiocyanate
CAS No.:632323-36-5
Molecular Formula:C₂₂H₂₁AuNPS
Molecular Weight:559.422
Hs Code.:

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Chemical Property of (tri(3-methylphenyl)phosphine)gold thiocyanate

Chemical Property:

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Technology Process of (tri(3-methylphenyl)phosphine)gold thiocyanate

There total 1 articles about (tri(3-methylphenyl)phosphine)gold thiocyanate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

: 134097-36-2
(tri-m-tolylphosphine)gold(I) chloride

: 333-20-0
potassium thioacyanate

: 632323-36-5
(tri(3-methylphenyl)phosphine)gold thiocyanate

Guidance literature:: In dichloromethane; water; byproducts: KCl; (N2); soln. of Au complex in CH2Cl2 and KSCN in water were mixed; mixt. was stirred at 20°C for 3 h; aq. phase septd.; extd. (CH2Cl2); org. phases combined and washed (H2O);dried (MgSO4); solvent evapd. (vac.); pentane added; cooled to -30.degr ee.C overnight; filtered; dried (vac.); recrystd. (CH2Cl2/pentane); elem. anal.;
DOI:10.1016/S0020-1693(03)00144-0

Reference yield: 86.0%

: 26042-64-8
silver hexafluoroantimonate

: 134097-36-2
(tri-m-tolylphosphine)gold(I) chloride

: 632323-36-5
(tri(3-methylphenyl)phosphine)gold thiocyanate

: 632323-44-5
(μ-thiocyanato)-bis[(tri(3-methylphenyl)phosphine)gold] hexafluoroantimonate

Guidance literature:: In dichloromethane; (N2); Au-Cl complex was treated with AgSbF6 in CH2Cl2 at -78°C for 30 min; filtered; filtrate was added to soln. of Au-SeCN complex in CH2Cl2; mixt. was stirred at -78°C for 3 h in dark; solvent concd. (vac.); pentane added at -30°C; filtered; dried (vac.); elem. anal.;
DOI:10.1016/S0020-1693(03)00144-0