(η5-pentamethylcyclopentadienyl)(methyl diphenylphosphinite)bis(acetonitrile)ruthenium(II) PF6

Base Information

Chemical Name:(η5-pentamethylcyclopentadienyl)(methyl diphenylphosphinite)bis(acetonitrile)ruthenium(II) PF6
CAS No.:918134-40-4
Molecular Formula:C₂₇H₃₄N₂OPRu*F₆P
Molecular Weight:679.588
Hs Code.:

Synonyms:

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Chemical Property of (η5-pentamethylcyclopentadienyl)(methyl diphenylphosphinite)bis(acetonitrile)ruthenium(II) PF6

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Technology Process of (η5-pentamethylcyclopentadienyl)(methyl diphenylphosphinite)bis(acetonitrile)ruthenium(II) PF6

There total 1 articles about (η5-pentamethylcyclopentadienyl)(methyl diphenylphosphinite)bis(acetonitrile)ruthenium(II) PF6 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 4020-99-9
diphenylphosphinous acid methyl ester

: tris(acetonitrile)pentamethylcyclopentadienylruthenium(II) hexafluorophosphate

: 918134-40-4
(η5-pentamethylcyclopentadienyl)(methyl diphenylphosphinite)bis(acetonitrile)ruthenium(II) PF6

Guidance literature:: In dichloromethane; acetonitrile; (Ar), ligand added to Ru complex in cold (-80°C) CH2Cl2 and CH3CN, stirred overnight at room temp.; evapd.(vac.), dissolved (CH2Cl2), crystd.(Et2O), elem. anal.;
DOI:10.1002/ejic.200501051

Reference yield: 85.0%

: 53101-38-5
3-chloro-1-hexene

: 37658-00-7
(E)-1-chloro-2-hexene

: 918134-40-4
(η5-pentamethylcyclopentadienyl)(methyl diphenylphosphinite)bis(acetonitrile)ruthenium(II) PF6

: 918134-60-8
ruthenium(IV)Cl(η5-pentamethylcyclopentadienyl)(Ph2(MeO)P)(η3-C3H7CHCHCH2) (PF6)

Guidance literature:: In dichloromethane; (Ar), excess of ligand (4:1 mixt. of 1-chloro-2-hexene and 3-chloro-1-hexene) added to Ru complex in CH2Cl2, stirred for 1 h; crystd.(Et2O), elem. anal.;
DOI:10.1002/ejic.200501051

Reference yield: 84.0%

: 563-52-0,35729-37-4
2-chloro-3-butene

: 918134-40-4
(η5-pentamethylcyclopentadienyl)(methyl diphenylphosphinite)bis(acetonitrile)ruthenium(II) PF6

: 918134-56-2
ruthenium(IV)Cl(η5-pentamethylcyclopentadienyl)(Ph2(MeO)P)(η3-CH3CHCHCH2) (PF6)

Guidance literature:: In dichloromethane; (Ar), excess of ligand added to Ru complex in CH2Cl2, stirred for 1 h; crystd.(Et2O), elem. anal.;
DOI:10.1002/ejic.200501051