[Ru(PhCO₂)(CO)2(py)]2

Base Information

Chemical Name:[Ru(PhCO₂)(CO)2(py)]2
CAS No.:106223-01-2
Molecular Formula:C₂₈H₂₀N₂O₈Ru₂
Molecular Weight:714.615
Hs Code.:

Synonyms:

Suppliers and Price of [Ru(PhCO₂)(CO)2(py)]2

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of [Ru(PhCO₂)(CO)2(py)]2

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

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Technology Process of [Ru(PhCO₂)(CO)2(py)]2

There total 2 articles about [Ru(PhCO₂)(CO)2(py)]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 59.0%

: 110-86-1
pyridine

: 532-32-1
sodium benzoate

: dicarbonyldichlororuthenium

: 106223-01-2
[Ru(PhCO₂)(CO)2(py)]2

Guidance literature:: In methanol; (under N2); Ru complex added to soln. C6H5CO2Na in degassed MeOH, heated at 120°C for 2.5 h; pyridine added, heated 5 min, cooled to -10°C; solid isolated; washed (ice-cold MeOH); dried (air) at 70°C; elem. anal.;
DOI:10.1039/b002304n

Reference yield: 8.0%

: 110-86-1
pyridine

: 532-32-1
sodium benzoate

: dicarbonyldichlororuthenium

: 106223-01-2
di-μ-benzoato-bis[dicarbonyl(pyridine)ruthenium(I)]

Guidance literature:: In methanol; react. of (Ru(CO)2Cl2)n, NaOC(O)Ph, and pyridine (1.01:9.7:1.29 mol) in MeOH according to Kepert, C. M., Deacon, G. B., Spiccia, L., Fallon, G. D., Sckelton, B. W., White, A. H. J. Chem. Soc. Dalton Trans., 2000, p. 2867-2874.; elem. anal.;
DOI:10.1107/S0108270103023709

Reference yield: 87.0%

: ammonium hexafluorophosphate

: 3002-81-1
5, 6-dimethyl-1,10-phenanthroline

: 106223-01-2
[Ru(PhCO₂)(CO)2(py)]2

: 663626-31-1
μ-O,O'-benzoatodi-μ-C,C-carbonyl-di-C,C-carbonylbis(5,6-dimethyl-1,10-phenanthroline)diruthenium(I) hexafluorophosphate

Guidance literature:: In methanol; Ru complex and ligand suspended in MeOH, sonicated, sealed, heated at 40°C; NH4PF6 added, sonicated, filtered, washed with cold EtOH and H2O, dried in air at 70°C;
DOI:10.1021/ic0348401