hydridocobalt tetracarbonyl

Base Information

• Chemical Name: hydridocobalt tetracarbonyl
• CAS No.: 64519-62-6
• Molecular Formula: C₄HCoO₄
• Molecular Weight: 172.043
• Mol file: 64519-62-6.mol

Synonyms:

Chemical Property of hydridocobalt tetracarbonyl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of hydridocobalt tetracarbonyl

There total 15 articles about hydridocobalt tetracarbonyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 37.0%

dicobalt octacarbonyl (15226-74-1,61091-28-9,61117-58-6) + Fe(Si(CH3)H2)2(CO)4 → iron pentacarbonyl (13463-40-6,37220-42-1) + cobalt tetracarbonyl hydride (64519-62-6,16842-03-8) + tetracobaltdodecacarbonyl (15041-50-6) + Co4(μ-SiMe)2(CO)11

Guidance literature:

In pentane; byproducts: H2, CO; (N2); 48 h, room temp.; extn. (pentane), extn. (CH2Cl2), recrystn. (CH2Cl2/pentane);

DOI:10.1016/0022-328X(93)83076-8

Reference yield: 37.0%

dicobalt octacarbonyl (15226-74-1,61091-28-9,61117-58-6) + (η5-C5H5)Fe(CO)2SiMe2H (32731-69-4) → di(cyclopentadienideiron dicarbonyl) (38117-54-3) + cobalt tetracarbonyl hydride (64519-62-6,16842-03-8) + cyclopentadienylirondicarbonyl hydride (35913-82-7)

Guidance literature:

In benzene; under N2, soln. of Co2(CO)8 was added dropwise over 15 min to a soln. of an equimolar amount of Fe-complex, stirred for 1 d under exclusion of light; separated from insoluble materials, solvent evapd. together with HCo(CO)4 and HFe(CO)2(C5H5), put into pentane, cooled to -78°C;

Reference yield:

(hydroxymethyl)cobalt tetracarbonyl (119146-93-9) → formaldehyd (50-00-0,30525-89-4,61233-19-0) + dicobalt octacarbonyl (15226-74-1,61091-28-9,61117-58-6) + hydridocobalt tetracarbonyl (16842-03-8,64519-62-6)

Guidance literature:

In dichloromethane; pentane; decompn. at -20°C;

DOI:10.1021/om00106a035

upstream raw materials:

dicobalt octacarbonyl

(trimethylsilyl)cobalt tetracarbonyl

isobutyraldehyde

isobutyrylcobalt tetracarbonyl

Downstream raw materials:

2-chloro-2-butenal

dicobalt octacarbonyl

isobutyraldehyde

methanol