(1beta,2beta,7beta,8beta)-Tricyclo[6.2.1.02,7]undeca-9-ene-3-one

Base Information

Chemical Name:(1beta,2beta,7beta,8beta)-Tricyclo[6.2.1.02,7]undeca-9-ene-3-one
CAS No.:115795-03-4
Molecular Formula:C₁₁H₁₄O
Molecular Weight:162.232
Hs Code.:
DSSTox Substance ID:DTXSID801143172
Nikkaji Number:J1.709.141G

Synonyms:DTXSID801143172;(1beta,2beta,7beta,8beta)-Tricyclo[6.2.1.02,7]undeca-9-ene-3-one;rel-(1R,4S,4aR,8aS)-4,4a,6,7,8,8a-Hexahydro-1,4-methanonaphthalen-5(1H)-one;115795-03-4

Suppliers and Price of (1beta,2beta,7beta,8beta)-Tricyclo[6.2.1.02,7]undeca-9-ene-3-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Total 0 raw suppliers

Chemical Property of (1beta,2beta,7beta,8beta)-Tricyclo[6.2.1.02,7]undeca-9-ene-3-one

Chemical Property:

XLogP3:1.9
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:0
Exact Mass:162.104465066
Heavy Atom Count:12
Complexity:254

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1CC2C3CC(C2C(=O)C1)C=C3
Isomeric SMILES:C1C[C@@H]2[C@H]3C[C@@H]([C@@H]2C(=O)C1)C=C3

Technology Process of (1beta,2beta,7beta,8beta)-Tricyclo[6.2.1.02,7]undeca-9-ene-3-one

There total 11 articles about (1beta,2beta,7beta,8beta)-Tricyclo[6.2.1.02,7]undeca-9-ene-3-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

: Methyl 5-(3-iodopropyl)bicyclo<2.2.2>hept-2-ene-6-carboxylate

: 51519-65-4,115795-03-4,115795-04-5,127062-97-9,127062-98-0,127708-33-2
endo-Tricyclo<6.2.1.0^2,7>-8-undecen-2-one

Guidance literature:: With samarium diiodide; tris(dibenzoylmethano)iron(III); In tetrahydrofuran; for 0.5h;
DOI:10.1021/jo00077a053

Reference yield: 68.0%

: 930-68-7
cyclohexenone

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 51519-65-4,115795-03-4,115795-04-5,127062-97-9,127062-98-0,127708-33-2
endo-Tricyclo<6.2.1.0^2,7>-8-undecen-2-one

Guidance literature:: With trifluorormethanesulfonic acid; In dichloromethane; at -40 ℃; for 5.5h; optical yield given as %de; diastereoselective reaction; Inert atmosphere;
DOI:10.1021/ja211856m

Reference yield:

: 930-68-7
cyclohexenone

: 542-92-7,25568-84-7,7313-32-8
cyclopenta-1,3-diene

: 77-73-6,933-60-8,1755-01-7,25038-78-2
bi(cyclopentadiene)

: 51519-62-1
Tricyclo<6.3.0^2,7.0>-undeca-9-en-3-one

: 51519-65-4,115795-03-4,115795-04-5,127062-97-9,127062-98-0,127708-33-2
tricyclo[6.2.1.0^2,7]undec-9-en-3-one

: 4-Cyclopent-2-enyl-3a,4,7,7a-tetrahydro-1H-4,7-methano-indene

Guidance literature:: With cetyltrimethylammonim bromide; In water; at 6 ℃; Further byproducts given; Irradiation;
DOI:10.1016/S0040-4020(01)87845-5