4-formylbenzoyloxymethylene-o-C-carborane

Base Information

• Chemical Name: 4-formylbenzoyloxymethylene-o-C-carborane
• CAS No.: 1373552-99-8
• Molecular Formula: C₁₁H₁₈B₁₀O₃
• Molecular Weight: 306.372
• Mol file: 1373552-99-8.mol

Synonyms:

Chemical Property of 4-formylbenzoyloxymethylene-o-C-carborane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-formylbenzoyloxymethylene-o-C-carborane

There total 1 articles about 4-formylbenzoyloxymethylene-o-C-carborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

(1'-hydroxymethyl)-1,2-dicarba-closo-dodecaborane (19610-34-5) + 4-formylbenzoyl chloride (16173-52-7) → 4-formylbenzoyloxymethylene-o-C-carborane (1373552-99-8)

Guidance literature:

With pyridine; In diethyl ether; byproducts: pyridine*HCl; anhyd. pyridine in Et2O added to soln. of B-compd. and OCHC6H4COCl in anhyd. Et2O at 10-15°C over 30 min with stirring; stirred for 1 h; diluted with H2O; ether layer sepd.; washed with H2O and satd. NaHCO3 soln.; dried (MgSO4); concd.; crystd. from hexane; elem. anal.;

DOI:10.1134/S1070363212030085

Reference yield: 88.0%

4-formylbenzoyloxymethylene-o-C-carborane (1373552-99-8) + 4-phenylalanine (92-67-1) → (E)-o-carboranyl-C-methylene-4-[(4'-biphenyl)iminomethyl]benzoate

Guidance literature:

In methanol; mixt. of B compd. and amine in anhyd. MeOH refluxed for 30-45 min; cooled to 0-5°C; filtered through glass porous filter; washed with cold MeOH; dried in air for 6-8 h; elem. anal.;

DOI:10.1134/S1070363212030085

Reference yield: 88.0%

4-formylbenzoyloxymethylene-o-C-carborane (1373552-99-8) + 4-amino-benzoic acid (150-13-0,159246-81-8,8014-65-1) → (E)-o-carboranyl-C-methylene-4-[(4'-HO2CC6H4)iminomethyl]benzoate

Guidance literature:

In methanol; mixt. of B compd. and amine in anhyd. MeOH refluxed for 30-45 min; cooled to 0-5°C; filtered through glass porous filter; washed with cold MeOH; dried in air for 6-8 h; elem. anal.;

DOI:10.1134/S1070363212030085

upstream raw materials:

(1'-hydroxymethyl)-1,2-dicarba-closo-dodecaborane

4-formylbenzoyl chloride

Refernces