cyclofuntumienol benzoate

Base Information

• Chemical Name: cyclofuntumienol benzoate
• CAS No.: 112515-96-5
• Molecular Formula: C₃₈H₅₆O₂
• Molecular Weight: 544.861
• Mol file: 112515-96-5.mol

Synonyms:

Chemical Property of cyclofuntumienol benzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of cyclofuntumienol benzoate

There total 9 articles about cyclofuntumienol benzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

Benzoic acid (3S,4S,5S,8S,9S,10R,13R,14S)-17-((1R,4R)-4-isopropyl-1-methyl-5-phenoxythiocarbonyloxy-hexyl)-4,13,14-trimethyl-tetradecahydro-cyclopropa[9,10]cyclopenta[a]phenanthren-3-yl ester (98183-25-6,112652-55-8,112652-57-0) → cyclofuntumienol benzoate (112515-96-5) + 24S-dihydrocyclofuntumienol benzoate (98155-98-7,98302-98-8,98303-02-7)

Guidance literature:

With tri-n-butyl-tin hydride; In toluene; at 130 ℃; for 4h;

Reference yield:

benzoyl chloride (98-88-4) → cyclofuntumienol benzoate (112515-96-5)

Guidance literature:

Multi-step reaction with 5 steps

1: 5 mg / pyridine / Ambient temperature

2: 5.5 mg / osmium tetroxide / Ambient temperature

3: 1) HIO₄, 2) NaBH₄ / 1) dioxane-water, 8 min, ice-cooling; 2) MeOH, 30 min

4: 3.5 mg / pyridine / 12 h / Ambient temperature

5: 0.01 mg / tributyltin hydride / toluene / 4 h / 130 °C

With pyridine; sodium tetrahydroborate; osmium(VIII) oxide; tri-n-butyl-tin hydride; periodic acid; In pyridine; toluene;

Reference yield:

cyclohomonervilol (78330-51-5) → cyclofuntumienol benzoate (112515-96-5)

Guidance literature:

Multi-step reaction with 5 steps

1: 5 mg / pyridine / Ambient temperature

2: 5.5 mg / osmium tetroxide / Ambient temperature

3: 1) HIO₄, 2) NaBH₄ / 1) dioxane-water, 8 min, ice-cooling; 2) MeOH, 30 min

4: 3.5 mg / pyridine / 12 h / Ambient temperature

5: 0.01 mg / tributyltin hydride / toluene / 4 h / 130 °C

With pyridine; sodium tetrahydroborate; osmium(VIII) oxide; tri-n-butyl-tin hydride; periodic acid; In pyridine; toluene;

upstream raw materials:

cyclohomonervilol benzoate

Benzoic acid (3S,4S,5S,9S,10R,13R,14S)-17-((1R,4S)-5,6-dihydroxy-4-isopropyl-1,5-dimethyl-hexyl)-4,13,14-trimethyl-tetradecahydro-cyclopropa[9,10]cyclopenta[a]phenanthren-3-yl ester

Benzoic acid (3S,4S,5S,8S,9S,10R,13R,14S)-17-((1R,4R)-4-isopropyl-1-methyl-5-phenoxythiocarbonyloxy-hexyl)-4,13,14-trimethyl-tetradecahydro-cyclopropa[9,10]cyclopenta[a]phenanthren-3-yl ester

benzoyl chloride

Downstream raw materials:

24S-dihydrocyclofuntumienol benzoate