(E)-styrylmercury bromide

Base Information

• Chemical Name: (E)-styrylmercury bromide
• CAS No.: 57917-66-5
• Molecular Formula: C₈H₇BrHg
• Molecular Weight: 383.638
• Mol file: 57917-66-5.mol

Synonyms:

Chemical Property of (E)-styrylmercury bromide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (E)-styrylmercury bromide

There total 1 articles about (E)-styrylmercury bromide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

[(E)-2-bromoethenyl]benzene (588-72-7,1340-14-3) + mercury dibromide → (E)-styrylmercury bromide (57917-66-5,68356-64-9,57917-65-4)

Guidance literature:

In tetrahydrofuran; vinyl bromide added to THF contg. Mg turnings until initiation occured, remainder of vinyl bromide added during 1h at reflux under N2, refluxed for further 1h, soln. transferred dropwise to soln. of HgBr2 at reflux, heated for 1h, stirred at room temp.; filtered, washed (THF), evapd., crystd. (EtOH);

DOI:10.1039/P19880002847

Reference yield: 89.0%

(E)-styrylmercury bromide (57917-66-5,68356-64-9,57917-65-4) + silver(I) acetate (563-63-3) → (E)-styrylmercury acetate (61185-54-4,63242-55-7,61185-53-3)

Guidance literature:

In chloroform; stirring (overnight, darkness); filtration (Celite), evapn., crystn. (heptane); elem. anal.;

Reference yield: 56.0%

(E)-styrylmercury bromide (57917-66-5,68356-64-9,57917-65-4) → (E,E)-distyrylmercury (64984-50-5,67445-41-4)

Guidance literature:

With potassium iodide; In water; acetone; soln. of KI in acetone and water added to soln. of Hg-compd. in acetone, pptn., stirred for 3h; collected, crystn. (heptane); elem. anal.;

DOI:10.1039/P19880002847

upstream raw materials:

[(E)-2-bromoethenyl]benzene

Downstream raw materials:

(E,E)-distyrylmercury

(E)-styrylmercury acetate