(cis-6,17-diphenyl-6,17-diphospha-2,13-dithiatricyclo{16.4.0.0(7.12)}docosa-7(12),8,10,1(18),19,21-hexaene-κ(2)S,κ(2)P)platinum(II) dihexafluorophosphate

Base Information

Chemical Name:(cis-6,17-diphenyl-6,17-diphospha-2,13-dithiatricyclo{16.4.0.0(7.12)}docosa-7(12),8,10,1(18),19,21-hexaene-κ(2)S,κ(2)P)platinum(II) dihexafluorophosphate
CAS No.:94904-42-4
Molecular Formula:C₃₀H₃₀P₂PtS₂*2F₆P
Molecular Weight:1001.66
Hs Code.:

(cis-6,17-diphenyl-6,17-diphospha-2,13-dithiatricyclo{16.4.0.0(7.12)}docosa-7(12),8,10,1(18),19,21-hexaene-κ(2)S,κ(2)P)platinum(II) dihexafluorophosphate

Synonyms:

Suppliers and Price of (cis-6,17-diphenyl-6,17-diphospha-2,13-dithiatricyclo{16.4.0.0(7.12)}docosa-7(12),8,10,1(18),19,21-hexaene-κ(2)S,κ(2)P)platinum(II) dihexafluorophosphate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (cis-6,17-diphenyl-6,17-diphospha-2,13-dithiatricyclo{16.4.0.0(7.12)}docosa-7(12),8,10,1(18),19,21-hexaene-κ(2)S,κ(2)P)platinum(II) dihexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (cis-6,17-diphenyl-6,17-diphospha-2,13-dithiatricyclo{16.4.0.0(7.12)}docosa-7(12),8,10,1(18),19,21-hexaene-κ(2)S,κ(2)P)platinum(II) dihexafluorophosphate

There total 2 articles about (cis-6,17-diphenyl-6,17-diphospha-2,13-dithiatricyclo{16.4.0.0(7.12)}docosa-7(12),8,10,1(18),19,21-hexaene-κ(2)S,κ(2)P)platinum(II) dihexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 18.0%

: 12080-32-9
dichloro(1,5-cyclooctadiene)platinum(ll)

: 94890-89-8
cis-6,17-diphenyl-6,17-diphospha-2,13-dithiatricyclo{16.4.0.0(7.12)}docosa-7⁽¹²⁾,8,10,1⁽¹⁸⁾,19,21-hexaene

: hexafluorophosphate anion

: 94904-42-4
(cis-6,17-diphenyl-6,17-diphospha-2,13-dithiatricyclo{16.4.0.0(7.12)}docosa-7(12),8,10,1(18),19,21-hexaene-κ(2)S,κ(2)P)platinum(II) dihexafluorophosphate

Guidance literature:: In ethanol; dichloromethane; addn. of (1,5-cyclooctadiene) platinum(II) dichloride to a stirred soln. of phosphino-ligand in CH2Cl2, treating with 95% EtOH to give a clear soln., addn. of PF6(1-)-salt in EtOH, stirring for 2 h; filtration, concg., recrystn. (MeCN/C6H6), elem. anal.;

Reference yield: 17.0%

: 12080-32-9
dichloro(1,5-cyclooctadiene)platinum(ll)

: 26042-63-7
silver(I) hexafluorophosphate

: 94890-89-8
cis-6,17-diphenyl-6,17-diphospha-2,13-dithiatricyclo{16.4.0.0(7.12)}docosa-7⁽¹²⁾,8,10,1⁽¹⁸⁾,19,21-hexaene

: 94904-42-4
(cis-6,17-diphenyl-6,17-diphospha-2,13-dithiatricyclo{16.4.0.0(7.12)}docosa-7(12),8,10,1(18),19,21-hexaene-κ(2)S,κ(2)P)platinum(II) dihexafluorophosphate

Guidance literature:: In ethanol; dichloromethane; AgPF6 is added to a soln. of macrocycle and (1,5-cyclooctadiene)PtCl2 in ethanol and CH2Cl2; concn. and extn. with MeCN, filtn. through celite and concn., resulting solid is recrystd. from MeCN/benzene, then dried at 80°C for 1 h under high vac., elem. anal.;
DOI:10.1021/ja00293a052