1,1'''-bis(diphenylphosphanyl)biferrocene

Base Information

Chemical Name:1,1'''-bis(diphenylphosphanyl)biferrocene
CAS No.:507233-71-8
Molecular Formula:C₄₄H₃₆Fe₂P₂
Molecular Weight:738.411
Hs Code.:

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Chemical Property of 1,1'''-bis(diphenylphosphanyl)biferrocene

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Technology Process of 1,1'''-bis(diphenylphosphanyl)biferrocene

There total 1 articles about 1,1'''-bis(diphenylphosphanyl)biferrocene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 68.0%

: 1',1'''-dilithiobiferrocene

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 507233-71-8
1,1'''-bis(diphenylphosphanyl)biferrocene

Guidance literature:: In tetrahydrofuran; under N2, 3 equiv. of P-compd. in THF was added dropwise to Fe-compd. soln. in THF at -80 °C for 4 h, stirring at room temp. for 4 h; soln. was filtered, evapd., residue was taken in CHCl3, concn., Et2O wasadded, solid was recrystd. from CHCl3/MeCN (:1, v/v), elem. anal.;
DOI:10.1002/1099-0682(200212)2002:12<3197::AID-EJIC3197>3.0.CO;2-T

Reference yield: 85.8%

: 7782-49-2
selenium

: 507233-71-8
1,1'''-bis(diphenylphosphanyl)biferrocene

: 1364682-05-2
(η5-C5H4PPh2Se)Fe(η5-C5H4)(η5-C5H4)Fe(η5-C5H4PPh2Se)

Guidance literature:: In toluene; under N2 or Ar; Se (2.4 equiv.) added to toluene soln. of Fe complex; stirred at 100°C for 5 h; cooled to ambient temp.; filtered through Celite; volatiles removed from filtrate under vac.; elem. anal.;
DOI:10.1021/om201220w

Reference yield: 79.0%

: dichloro(pentamethylcyclopentadienyl)rhodium (III) dimer

: 75-09-2
dichloromethane

: 507233-71-8
1,1'''-bis(diphenylphosphanyl)biferrocene

: [(η(5)-C5Me5)RhCl(μ-Cl)]2(1,1'''-bis(diphenylphosphanyl)biferrocene)

Guidance literature:: In dichloromethane; under N2, 1 equiv. of Fe-compd. in CH2Cl2 was added to Rh-compd. soln. in CH2Cl2, stirring at room temp. for 5 h; soln. was evapd., residue was recrystd. from CH2Cl2/Et2O (1:1, v/v), elem. anal.;
DOI:10.1002/1099-0682(200212)2002:12<3197::AID-EJIC3197>3.0.CO;2-T