(1S,3S)-2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropanecarboxylic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester

Base Information

• Chemical Name: (1S,3S)-2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropanecarboxylic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester
• CAS No.: 139068-78-3
• Molecular Formula: C₂₀H₃₄O₂
• Molecular Weight: 306.489
• Mol file: 139068-78-3.mol

Synonyms:

Chemical Property of (1S,3S)-2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropanecarboxylic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1S,3S)-2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropanecarboxylic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester

There total 2 articles about (1S,3S)-2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropanecarboxylic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

2,5-Dimethyl-2,4-hexadiene (764-13-6) + d-menthyl diazoacetate (65437-23-2) → (1R,3R)-2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropanecarboxylic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester (65437-24-3) + (1R,3S)-2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropanecarboxylic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester (65437-27-6) + (1S,3R)-2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropanecarboxylic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester (16736-58-6,40999-13-1,40999-14-2,63323-85-3,63323-86-4,65437-24-3,65437-25-4,65437-27-6,65437-28-7,139068-78-3) + (1S,3S)-2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropanecarboxylic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester (139068-78-3)

Guidance literature:

Cu(I) complex of bis-oxazoline 7; In dichloromethane; at 23 ℃; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1016/0040-4039(91)80110-R

Reference yield:

2,5-Dimethyl-2,4-hexadiene (764-13-6) + d-menthyl diazoacetate (65437-23-2) → (1R,3R)-2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropanecarboxylic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester (65437-24-3) + (1R,3S)-2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropanecarboxylic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester (65437-27-6) + (1S,3R)-2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropanecarboxylic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester (16736-58-6,40999-13-1,40999-14-2,63323-85-3,63323-86-4,65437-24-3,65437-25-4,65437-27-6,65437-28-7,139068-78-3) + (1S,3S)-2,2-Dimethyl-3-(2-methyl-propenyl)-cyclopropanecarboxylic acid (1S,2R,5S)-2-isopropyl-5-methyl-cyclohexyl ester (139068-78-3)

Guidance literature:

Cu(I) complex of bis-oxazoline 7; In dichloromethane; at 23 ℃; Yield given. Yields of byproduct given. Title compound not separated from byproducts;

DOI:10.1016/0040-4039(91)80110-R

upstream raw materials:

2,5-Dimethyl-2,4-hexadiene

d-menthyl diazoacetate