65437-23-2Relevant academic research and scientific papers
Enantioselective Copper-Catalyzed Oxy-Alkynylation of Diazo Compounds
Hari, Durga Prasad,Waser, Jerome
, p. 8420 - 8423 (2017)
Enantioselective catalytic methods allowing the addition of both a nucleophile and an electrophile onto diazo compounds give a fast access into important building blocks. Herein, we report the highly enantioselective oxyalkynylation of diazo compounds usi
Semicorrin Metal Complexes as Enantioselective Catalysts. Part 2. Enantioselective Cyclopropane Formation from Olefins with Diazo Compounds Catalyzed by Chiral (Semicorrinato)copper Complexes)
Fritschi, Hugo,Leutenegger, Urs,Pfaltz, Andreas
, p. 1553 - 1565 (2007/10/02)
Copper complexes of chiral, C2-symmetric semicorrin ligands were found to be efficient catalysts for the cyclopropane formation from olefins with diazo compounds.In the presence of 1 mol-percent of catalyst, alkyl diazoacetates reacted smoothly with termi
