Tris(2,2-dimethylpropyl)gallane

Base Information

Chemical Name:Tris(2,2-dimethylpropyl)gallane
CAS No.:106136-97-4
Molecular Formula:C15H33Ga
Molecular Weight:283.15
Hs Code.:
DSSTox Substance ID:DTXSID50548200

Synonyms:trisneopentylgallium;Tris(2,2-dimethylpropyl)gallane;106136-97-4;DTXSID50548200;MDDLDNKWFHKJMP-UHFFFAOYSA-N

Suppliers and Price of Tris(2,2-dimethylpropyl)gallane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
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Total 0 raw suppliers

Chemical Property of Tris(2,2-dimethylpropyl)gallane

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:6
Exact Mass:282.18380
Heavy Atom Count:16
Complexity:159

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)C[Ga](CC(C)(C)C)CC(C)(C)C

Technology Process of Tris(2,2-dimethylpropyl)gallane

There total 5 articles about Tris(2,2-dimethylpropyl)gallane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 13450-90-3
Gallium trichloride

: 7412-67-1
neopentyl lithium

: 106136-97-4
trineopentyl gallium

Guidance literature:: In hexane; under Ar, 3 equiv. of Li-compd., reflux in n-hexane for 16 h;
DOI:10.1002/1521-3749(200206)628:5<1001::AID-ZAAC1001>3.0.CO;2-N

Reference yield: 68.0%

: 123-91-1,28347-88-8,28347-91-3,39449-24-6,54841-74-6
1,4-dioxane

: 13450-88-9
gallium(III) bromide

: 7412-67-1
neopentyl lithium

: 106136-97-4
trineopentyl gallium

: 129286-98-2
lithium-tetraneopentylgallanate-dioxane

Guidance literature:: In pentane; byproducts: LiBr; added dioxane at 0°C, added in the dark at 0°C LiCH2CMe3 over 50 min, stirred for 2.5 h at room temperature; filtered, volume reduced, cooled to -30°C, elem. anal.;

Reference yield: 48.0%

: 68317-89-5
Ga₂Br₄(dioxane)2

: 7412-67-1
neopentyl lithium

: 106136-97-4
trineopentyl gallium

Guidance literature:: In diethyl ether; pentane; byproducts: Ga, LiBr; added at -60°C, warmed up to room temperature, stirred for 30 min; solvent removed by destillation, filtered, fractionated destillation;