1-((1-ethyl-benzimidazol-2-yl)methyl)-3-benzylimidazolium chloride

Base Information

• Chemical Name: 1-((1-ethyl-benzimidazol-2-yl)methyl)-3-benzylimidazolium chloride
• CAS No.: 1236065-06-7
• Molecular Formula: C₂₀H₂₁N₄*Cl
• Molecular Weight: 352.867
• Mol file: 1236065-06-7.mol

Synonyms:

Chemical Property of 1-((1-ethyl-benzimidazol-2-yl)methyl)-3-benzylimidazolium chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-((1-ethyl-benzimidazol-2-yl)methyl)-3-benzylimidazolium chloride

There total 1 articles about 1-((1-ethyl-benzimidazol-2-yl)methyl)-3-benzylimidazolium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

1-benzylimidazole (4238-71-5) + 2-(chloromethyl)-1-ethyl-1H-benzo[d]imidazole (66947-93-1) → 1-((1-ethyl-benzimidazol-2-yl)methyl)-3-benzylimidazolium chloride (1236065-06-7)

Guidance literature:

In dimethyl sulfoxide; at 120 ℃; for 24h;

DOI:10.1039/c000722f

Reference yield: 92.0%

1-((1-ethyl-benzimidazol-2-yl)methyl)-3-benzylimidazolium chloride (1236065-06-7) + palladium diacetate (3375-31-3) → [Pd(1-(1-ethyl-benzimidazol-2-ylmethyl)-3-benzylimidazolin-2-ylidene)2][Cl]2

Guidance literature:

In dimethyl sulfoxide; soln. Pd(OAc)2 and imidazolium chloride in DMSO was stirred at room temp. for 2 h and then at 80°C for 12 h; soln. was concd., Et2O was added, ppt. was collected and washed with Et2O; elem. anal.;

DOI:10.1039/c000722f

Reference yield: 90.0%

1-((1-ethyl-benzimidazol-2-yl)methyl)-3-benzylimidazolium chloride (1236065-06-7) + nickel(II) acetate tetrahydrate (6018-89-9) → [Ni(1-(1-ethyl-benzimidazol-2-ylmethyl)-3-benzylimidazolin-2-ylidene)2][Cl]2

Guidance literature:

In dimethyl sulfoxide; soln. Ni(OAc)2*4H2O and imidazolium chloride in DMSO was stirred at roomtemp. for 2 h and then at 80°C for 12 h; soln. was concd., Et2O was added, ppt. was collected and washed with Et2O; elem. anal.;

DOI:10.1039/c000722f

upstream raw materials:

1-benzylimidazole

2-(chloromethyl)-1-ethyl-1H-benzo[d]imidazole