Technology Process of (HC[(CMe)(N-2,6-iPr2C6H3)]2)AlH(NH-2,6-iPr2C6H3)
There total 3 articles about (HC[(CMe)(N-2,6-iPr2C6H3)]2)AlH(NH-2,6-iPr2C6H3) which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
neat (no solvent);
byproducts: H2; under N2 atm. mixt. Al complex and aniline was heated to 150°C for 1 h; react. mixt. was cooled to room temp. and dissolved in toluene, solvent was removed in vacuo, residue was washed with n-hexane; elem. anal.;
DOI:10.1021/om050698v
- Guidance literature:
-
acetophenone p-toluenesulfonylhydrazone;
With
sodium hydride;
In
toluene; mineral oil;
at 20 ℃;
for 5h;
[(HC(CMeN(2,6-i-Pr2C6H3))2)AlH2];
In
toluene; mineral oil;
at 110 ℃;
for 10h;
Inert atmosphere;
DOI:10.1021/acs.organomet.8b00518
- Guidance literature:
-
Multi-step reaction with 2 steps
1.1: methanol / 20 °C
2.1: sodium hydride / mineral oil; toluene / 5 h / 20 °C
2.2: 10 h / 110 °C / Inert atmosphere
With
sodium hydride;
In
methanol; toluene; mineral oil;
DOI:10.1021/acs.organomet.8b00518
![[(HC(CMeN(2,6-i-Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>))2)AlH<sub>2</sub>]](/Databaselist/images/loading.webp)
