chlorido(5,10,15,20-tetramesitylporphyrinato^(1-))oxoiron(IV)

Base Information

• Chemical Name: chlorido(5,10,15,20-tetramesitylporphyrinato^(1-))oxoiron(IV)
• CAS No.: 77742-79-1
• Molecular Formula: C₅₆H₅₂ClFeN₄O
• Molecular Weight: 888.355
• Mol file: 77742-79-1.mol

Synonyms:

Chemical Property of chlorido(5,10,15,20-tetramesitylporphyrinato^(1-))oxoiron(IV)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of chlorido(5,10,15,20-tetramesitylporphyrinato^(1-))oxoiron(IV)

There total 3 articles about chlorido(5,10,15,20-tetramesitylporphyrinato^(1-))oxoiron(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

hydrogenchloride (7647-01-0,15364-23-5) + (5,10,15,20-tetramesitylporphyrinato)oxoiron(IV) (93085-16-6) → 5,10,15,20-tetra(2',4',6'-trimethylphenyl)porphyrinatoiron(III) chloride (136096-56-5,77439-21-5) + chlorido(5,10,15,20-tetramesitylporphyrinato(1-))oxoiron(IV) (77742-79-1,95724-71-3)

Guidance literature:

In dichloromethane; at -60 ℃; Reagent/catalyst; Solvent;

DOI:10.1021/jacs.9b13503

Reference yield:

nitrate(5,10,15,20-tetramesitylporphyrinato(1-))oxoiron(IV) + tetrabutyl-ammonium chloride (1112-67-0) → chlorido(5,10,15,20-tetramesitylporphyrinato(1-))oxoiron(IV) (77742-79-1,95724-71-3)

Guidance literature:

In dichloromethane-d2; byproducts: tetra-n-butylammonium nitrate; react. ammonium salt with Fe complex in CD2Cl2 at -60°C; detection by NMR;

DOI:10.1021/ic3006597

Reference yield:

5,10,15,20-tetra(2',4',6'-trimethylphenyl)porphyrinatoiron(III) chloride (136096-56-5,77439-21-5) + ozone (10028-15-6) → chlorido(5,10,15,20-tetramesitylporphyrinato(1-))oxoiron(IV) (77742-79-1,95724-71-3)

Guidance literature:

In dichloromethane; bubbling O3 through a soln. of Fe complex in CH2Cl2 at -80 to -30°C, bubbling Ar; not isolated;

DOI:10.1021/ic3006597

upstream raw materials:

tetrabutyl-ammonium chloride

5,10,15,20-tetra(2',4',6'-trimethylphenyl)porphyrinatoiron(III) chloride

ozone

hydrogenchloride

Downstream raw materials:

5,10,15,20-tetra(2',4',6'-trimethylphenyl)porphyrinatoiron(III) chloride