Fe(tetra-(2,4,6-trimethyl)porphyrin)Cl

Base Information

• Chemical Name: Fe(tetra-(2,4,6-trimethyl)porphyrin)Cl
• CAS No.: 136096-56-5
• Molecular Formula: C₅₆H₅₂ClFeN₄
• Molecular Weight: 872.356
• Mol file: 136096-56-5.mol

Synonyms:

Chemical Property of Fe(tetra-(2,4,6-trimethyl)porphyrin)Cl

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Fe(tetra-(2,4,6-trimethyl)porphyrin)Cl

There total 20 articles about Fe(tetra-(2,4,6-trimethyl)porphyrin)Cl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

iron(II) chloride tetrahydrate + 5,10,15,20-tetramesitylporphyrin → 5,10,15,20-tetra(2',4',6'-trimethylphenyl)porphyrinatoiron(III) chloride (136096-56-5,77439-21-5)

Guidance literature:

In N,N-dimethyl-formamide; porphyrine and FeCl2*4H2O in DMF was heated for 2h under reflux, pptn. on dropping aq. HCl into the soln.;; filtration, warm (50°C) DMF was added to the ppt., pptn. with aq. HCl, filtration, washed with aq. HCl and H2O, dried at 150°C and 0.1 Torr; elem. anal.;;

Reference yield: 88.0%

hydrogenchloride (7647-01-0,15364-23-5) + 5,10,15,20-tetramesitylporphyrin + iron(II) chloride → 5,10,15,20-tetra(2',4',6'-trimethylphenyl)porphyrinatoiron(III) chloride (136096-56-5,77439-21-5)

Guidance literature:

In methanol; dichloromethane; refluxing FeCl2 with porphyrin in CH2Cl2/MeOH=3:1 under N2 (TLC monitoring), solvent removal (reduced pressure), dissoln. in CH2Cl2, washing (water), chromy. (SiO2, CH2Cl2, then CH2Cl2/MeOH=9:1), evapn., dissoln. in CH2Cl2, bubbling HCl for 1 min; expelling HCl with N2, evapn.;

DOI:10.1016/s0020-1693(97)05597-7

Reference yield: 78.0%

[FeC20H7N4(C6H2(CH3)3)4(O)](1+)*Cl(1-)=[FeC20H7N4(C6H2(CH3)3)4(O)]Cl → 2,3-epoxynorbornane (278-74-0) + 5,10,15,20-tetra(2',4',6'-trimethylphenyl)porphyrinatoiron(III) chloride (136096-56-5,77439-21-5)

Guidance literature:

With nornborne; at -80°C;

DOI:10.1021/ja00400a075

upstream raw materials:

hydrogenchloride

styrene

chlorido(5,10,15,20-tetramesitylporphyrinato^(1-))oxoiron(IV)

(4-azo-(phenylcyanamido)benzene)(tetramesitylporphyrinato)iron(III)

Downstream raw materials:

hydroxo(5,10,15,20-tetrakis(mesityl)porphyrinato)iron(III)

Fe(tetraphenylporphyrinato)(1-methylimidazole)2⁽¹⁺⁾

(chlorido)(5,10,15,20-tetramesitylporphyrinato)iron(III)⁽¹⁺⁾

iron(II) meso-tetramesitylporphyrin