diphenylphosphino(phenyl pyridin-2-yl-methylene)amine palladium methyl chloride

Base Information

• Chemical Name: diphenylphosphino(phenyl pyridin-2-yl-methylene)amine palladium methyl chloride
• CAS No.: 872216-16-5
• Molecular Formula: C₂₅H₂₂ClN₂PPd
• Molecular Weight: 523.31
• Mol file: 872216-16-5.mol

Synonyms:

Chemical Property of diphenylphosphino(phenyl pyridin-2-yl-methylene)amine palladium methyl chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of diphenylphosphino(phenyl pyridin-2-yl-methylene)amine palladium methyl chloride

There total 1 articles about diphenylphosphino(phenyl pyridin-2-yl-methylene)amine palladium methyl chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

diphenylphosphino(phenyl pyridin-2-yl-methylene)amine + chloromethyl(1,5-cyclooctadiene)palladium(II) → diphenylphosphino(phenyl pyridin-2-yl-methylene)amine palladium methyl chloride (872216-16-5)

Guidance literature:

In dichloromethane; byproducts: Pd; (N2); using Schlenk techniques; stirring of C5H4NC(Ph)NPPh2 and PdCl(Me)(COD); cooling to -78°C; stirring, addn. dropwise of CH2Cl2; stirring at 15°C for 2 days in the dark; filtration, removal of CH2Cl2 under reduced pressure, washing with hexane, drying in vac., elem. anal.;

DOI:10.1016/j.jorganchem.2005.04.032

Reference yield: 91.0%

diphenylphosphino(phenyl pyridin-2-yl-methylene)amine palladium methyl chloride (872216-16-5) + sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1) → diphenylphosphino(phenyl pyridin-2-yl-methylene)amine methyl acetonitrile palladium(II) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate (872216-21-2)

Guidance literature:

In acetonitrile; (N2); using Schlenk techniques; sealing of mixt. of Pd(C5H4NC(Ph)NPPh2)Cl(Me), Na(B(3,5-(CF3)2-C6H3)4) and acetonitrile; sealing, stirring for 4days at room temp.; pptn., filtration, removal of solvent under reduced pressure, dissolvingin CH2Cl2, filtration, removal of solvent, drying in vac., elem. anal.;

DOI:10.1016/j.jorganchem.2005.04.032

Reference yield:

diphenylphosphino(phenyl pyridin-2-yl-methylene)amine palladium methyl chloride (872216-16-5) → diphenylphosphino(phenyl pyridin-2-yl-methylene)amine palladium N-tert-butyl-η1-iminoacyl-chloride (872216-27-8)

Guidance literature:

Multi-step reaction with 2 steps

1: chloroform-d1

2: chloroform-d1

In chloroform-d1;

DOI:10.1016/j.jorganchem.2005.04.032

Downstream raw materials:

diphenylphosphino(phenyl pyridin-2-yl-methylene)amine palladium η1-acyl chloride

diphenylphosphino(phenyl pyridin-2-yl-methylene)amine methyl acetonitrile palladium(II) tetrakis(3,5-bis(trifluoromethyl)phenyl)borate

diphenylphosphino(phenyl pyridin-2-yl-methylene)amine palladium N-tert-butyl-η1-iminoacyl-chloride