all-trans-[RuCl₂(CO)2(PPh₂OMe)2]

Base Information

Chemical Name:all-trans-[RuCl₂(CO)2(PPh₂OMe)2]
CAS No.:54205-77-5
Molecular Formula:C₂₈H₂₆Cl₂O₄P₂Ru
Molecular Weight:660.436
Hs Code.:

all-trans-[RuCl<sub>2</sub>(CO)2(PPh<sub>2</sub>OMe)2]

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Chemical Property of all-trans-[RuCl₂(CO)2(PPh₂OMe)2]

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Technology Process of all-trans-[RuCl₂(CO)2(PPh₂OMe)2]

There total 1 articles about all-trans-[RuCl₂(CO)2(PPh₂OMe)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 23.0%

: 14898-67-0
ruthenium(III) chloride trihydrate

: 201230-82-2
carbon monoxide

: 85324-78-3
1,2-bis(diphenylphosphine oxy)ethane

: 54205-77-5,960509-28-8
all-trans-[RuCl₂(CO)2(PPh₂OMe)2]

Guidance literature:: In methanol; under Ar, Schlenk techniques; CO bubbled through soln. of RuCl3*3H2O in MeOH under reflux for 0.5 h; cooling to room temp., addn. of excess Ph2POCH2CH2OPPh2; stirring for 24 h; solid filtered off and recrystd. from MeOH; elem. anal.;
DOI:10.1016/j.jorganchem.2007.09.007

Reference yield: 44.0%

: 16940-66-2
sodium tetrahydroborate

: 54205-77-5,960509-28-8
all-trans-[RuCl₂(CO)2(PPh₂OMe)2]

: 960378-99-8
all-trans-[RuH₂(CO)2(PPh₂OMe)2]

Guidance literature:: In ethanol; toluene; under Ar, Schlenk techniques; soln. of NaBH4 in EtOH (excess) added to soln. of RuCl2(CO)2(PPh2OMe)2 in toluene; stirring at room temp. for 12 h; evapn. to dryness; extn. with CH2Cl2; evapn. to dryness; trituration with EtOH; solid filtered off and recrystd. from EtOH; elem. anal.;
DOI:10.1016/j.jorganchem.2007.09.007