dirhodium(Cl)2(CO)2(μ-Ph2PCH2SCH3)2

Base Information

• Chemical Name: dirhodium(Cl)2(CO)2(μ-Ph2PCH2SCH3)2
• CAS No.: 114630-32-9
• Molecular Formula: C₃₀H₃₀Cl₂O₂P₂Rh₂S₂
• Molecular Weight: 825.364
• Mol file: 114630-32-9.mol

Synonyms:

Chemical Property of dirhodium(Cl)2(CO)2(μ-Ph2PCH2SCH3)2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of dirhodium(Cl)2(CO)2(μ-Ph2PCH2SCH3)2

There total 3 articles about dirhodium(Cl)2(CO)2(μ-Ph2PCH2SCH3)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 66.0%

di(rhodium)tetracarbonyl dichloride + diphenylphosphino(methylthio)methane (13119-14-7) → Rh2Cl2(CO)2((C6H5)2PCH2SCH3)2 (114630-32-9)

Guidance literature:

In acetone; Ph2PCH2SCH3 is dissolved in acetone (Ar), and Rh2(μ-Cl)2(CO)4 is added. The complex dissolved and, after a few minutes, a ppt. begins to form. The mixt. is refluxed for 10 min, then allowed to cool.; The orange ppt. is filtered. This is recrystd. from acetone to give the product. Elem. anal. The product may contain a mixt. of two stereoisomers or one pure isomer.;

DOI:10.1016/S0022-328X(00)99464-6

Reference yield:

(platinum(Cl)(Ph2PCH2SCH3)2)(rhodium(Cl)2(CO)2) (123455-00-5) → PtCl2CO(C6H5)2PCH2SCH3 (95823-89-5) + dirhodium(Cl)2(CO)2(μ-Ph2PCH2SCH3)2 (114630-32-9)

Guidance literature:

In chloroform-d1; byproducts: CO; warming of soln. from -50°C to ambient temp., standing for 1 h (under Ar);

DOI:10.1016/0022-328X(89)85416-6

Reference yield:

di(rhodium)tetracarbonyl dichloride + cis-platinum(Cl)2(Ph2PCH2SCH3)2 (95787-29-4,95840-67-8) → PtCl2CO(C6H5)2PCH2SCH3 (95823-89-5) + Rh2Cl2(CO)2((C6H5)2PCH2SCH3)2 (114630-32-9)

Guidance literature:

In chloroform-d1; The two complexes are allowed to react in CDCl3 soln.; The react. is monitored by (31)P-NMR.;

DOI:10.1016/S0022-328X(00)99464-6

upstream raw materials:

cis-platinum(Cl)2(Ph₂PCH₂SCH₃)2

diphenylphosphino(methylthio)methane

(platinum(Cl)(Ph₂PCH₂SCH₃)2)(rhodium(Cl)2(CO)2)