95823-89-5

Upstream product

• 95787-29-4 cis-platinum(Cl)2(Ph₂PCH₂SCH₃)2 
• 123455-00-5 (platinum(Cl)(Ph₂PCH₂SCH₃)2)(rhodium(Cl)2(CO)2) 
• 12080-32-9 dichloro(1,5-cyclooctadiene)platinum(ll) 
• 201230-82-2 carbon monoxide 
• 13119-14-7 diphenylphosphino(methylthio)methane 
• 95787-32-9 Pt₂Cl₂((C₆H₅)2PCH₂SCH₃)2 
• 1641-69-6 [13C]Carbon monoxide 

Downstream Products

• 114630-34-1 PtCl₂((C₆H₅)2PCH₂SCH₃) 

Relevant academic research and scientific papers

Reactions of (M = Pd or Pt) with . Preparation of a Ph2PCH2SCH3-bridged palladium-rhodium complex

When cis- and are allowed to react at ambient temperature cis- and are formed.By performing the reaction at -50 deg C the intermediate may be identified.In contrast reacts with to yield the mixed metal complex .

Platinum and rhodium complexes in which diphenylphosphino(methylthio)methane acts as a monodentate, chelated or bridging ligand

Reaction of with Ph2PCH2SCH3 yields cis- which, on treatment with AgBF4, is converted to BF4, in which one of the ligands is chelated.With , cis- reacts to give the platinum(I) complex , which contains a platinum-platinum bond.The terminal chlorides may be replaced by iodide, but the complex is cleaved by carbon monoxide. reacts with Ph2PCH2SCH3 to produce , whereas with Ph2PCH2CH2SCH3 it yields .A ligand exchange reaction occurs between cis- and to give cis- and .