13119-14-7

Upstream product

• 2373-51-5 chloro-methylsulfanyl-methane 
• 65567-06-8 lithium diphenylphosphide 
• 75-18-3 dimethylsulfide 
• 1079-66-9 chloro-diphenylphosphine 
• 15475-27-1 potassium diphenylphosphine 
• 124008-74-8 methylthiomethylphosphonous dichloride 

Downstream Products

• 13119-15-8 methylthiodiphenylphosphine oxide 
• 82287-70-5 NiCl₂((C₆H₅)2PCH₂SCH₃)2 
• 114384-82-6 {platinum(bis(diphenylphosphino)methane)(diphenylphosphino(methylthio)methane)}⁽²⁺⁾ 
• 101136-57-6 trans-tetracarbonylbis(methylthiomethyldiphenylphosphane)chromium⁽⁰⁾ 
• 180037-19-8 [Co2(μ-HCCO2Me)(CO)5(PPh2CH2SMe)] 
• 95823-89-5 PtCl₂CO(C₆H₅)2PCH₂SCH₃ 
• 95787-29-4 cis-platinum(Cl)2(Ph₂PCH₂SCH₃)2 
• 114630-32-9 Rh₂Cl₂(CO)2((C₆H₅)2PCH₂SCH₃)2 
• 95840-68-9 cis-(palladium(Cl)2(Ph₂PCH₂SCH₃)2) 
• 95787-33-0 trans-(palladium(Cl)2(Ph₂PCH₂SCH₃)2) 
• 101136-58-7 pentacarbonyl(methylthiomethyldiphenylphosphoniomethanide)chromium⁽⁰⁾ 
• 82287-16-9 NiBr₂((C₆H₅)2PCH₂SCH₃)2 
• 82287-16-9 NiBr₂((C₆H₅)2PCH₂SCH₃)2 
• 180037-18-7 [Co2(μ-MeO2CCCCO2Me)(CO)5(PPh2CH2SMe)] 

Relevant academic research and scientific papers

Convenient methods for the synthesis of a library of hemilabile phosphines

A series of novel functionalized phosphines of hemilabile character, R 2P(CH2)nZ, have been prepared from diarylphosphines using several synthetic methodologies. The synthetic methods include the alkylation of lithium diar

Platinum and rhodium complexes in which diphenylphosphino(methylthio)methane acts as a monodentate, chelated or bridging ligand

Reaction of with Ph2PCH2SCH3 yields cis- which, on treatment with AgBF4, is converted to BF4, in which one of the ligands is chelated.With , cis- reacts to give the platinum(I) complex , which contains a platinum-platinum bond.The terminal chlorides may be replaced by iodide, but the complex is cleaved by carbon monoxide. reacts with Ph2PCH2SCH3 to produce , whereas with Ph2PCH2CH2SCH3 it yields .A ligand exchange reaction occurs between cis- and to give cis- and .

PREPARATION AND REACTIONS OF METHYLTHIOMETHYL-SUBSTITUTED PHOSPHORUS HALIDES

Methylthiomethylphosphonous dichloride, MeSCH2PCl2 (1), is synthesized by the reaction of MeSCH2SnBun, with phosphorus trichloride.Substitution reactions to give MeSCH2PX2 (X = NEt2, OPri, F, Ph) are described.The phosphorus(III) compounds are readily converted to the corresponding phosphonyl and thiophosphonyl derivatives, MeSCH2P(Z)X2 (Z = O, S), and the phosphorane, MeSCH2PF4, respectively.Chlorination of the methylene group to give compounds of the type MeSCHClP(O)X2 and MeSCCl2P(O)X2 is reported.Key words: Methylthiomethylphosphorus compounds; phosphorus halides; carbon-tin cleavage