tri-p-tolylantimony iodine azide

Base Information

• Chemical Name: tri-p-tolylantimony iodine azide
• CAS No.: 106112-72-5
• Molecular Formula: C₂₁H₂₁IN₃Sb
• Molecular Weight: 564.072
• Mol file: 106112-72-5.mol

Synonyms:

Chemical Property of tri-p-tolylantimony iodine azide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of tri-p-tolylantimony iodine azide

There total 1 articles about tri-p-tolylantimony iodine azide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

iodine(I) azide (14696-82-3) + tri(p-tolyl)antimony (5395-43-7) → tri-p-tolylantimony iodine azide (106112-72-5)

Guidance literature:

In tetrachloromethane; addn. of freshly prepd. soln. of IN3 in CCl4 at -10°C to stirred soln. of (C6H4CH3)3Sb in CCl4 precooled to -10°C for 15 min under N2; stirring for 1 h at initial temp.; allowing to reach room temp.;; filtration; evapn. under reduced pressure; addn. of petroleum ether; cooling overnight; elem. anal.;;

DOI:10.1016/S0277-5387(00)84419-8

Reference yield:

tri-p-tolylantimony iodine azide (106112-72-5) + phenyl isocyanate (103-71-9) → 1-phenyl-4(tri-p-tolylantimony iodide)tetrazolinone (106112-80-5)

Guidance literature:

In neat (no solvent); careful heating of equimolar mixt. of antimony complex and C6H5NCO at 100°C for 4 h;; treatment with dried benzene; crystn.; elem. anal.; IR and UV spectroscopy;;

DOI:10.1016/S0277-5387(00)84419-8

upstream raw materials:

iodine(I) azide

tri(p-tolyl)antimony

Downstream raw materials:

1-phenyl-4(tri-p-tolylantimony iodide)tetrazolinone