14696-82-3 Usage
Description
Iodineazide is a chemical compound that consists of iodine and azide ions. It is known for its powerful explosive properties, making it a highly sensitive and unstable substance. Due to its reactivity to heat, shock, and friction, it is considered extremely hazardous and requires careful handling by trained professionals in controlled environments.
Uses
Used in Research Laboratories:
Iodineazide is used as a powerful explosive in research laboratories for specific applications that require its high energy output. Its sensitivity to various stimuli makes it suitable for controlled detonations in a research setting.
Used in Industrial Applications:
In some industrial applications, iodineazide is utilized as a component in explosive devices due to its high energy release. However, its use is limited due to the strict regulations and safety precautions required for handling this hazardous chemical.
Used as a Detonator:
Iodineazide is used as a detonator in initiating explosive devices because of its sensitivity to heat, shock, and friction. Its ability to trigger explosive reactions makes it a critical component in certain explosive systems.
Check Digit Verification of cas no
The CAS Registry Mumber 14696-82-3 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,4,6,9 and 6 respectively; the second part has 2 digits, 8 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 14696-82:
(7*1)+(6*4)+(5*6)+(4*9)+(3*6)+(2*8)+(1*2)=133
133 % 10 = 3
So 14696-82-3 is a valid CAS Registry Number.
InChI:InChI=1/IN3/c1-3-4-2
14696-82-3Relevant articles and documents
The [ICNI]+ cation: A combined experimental and theoretical study. Reaction of [ICNI]+[AsF6]- with CsN3
Klapoetke, Thomas M.
, p. 553 - 557 (2007/10/03)
(Iodocyano)iodine hexafluoroarsenate, [ICNI]+[AsF6]-, containing the linear 22-valence-electron [ICNI]+ cation was synthesized either by the reaction of iodine cyanide with [I3]+[AsF6]- or directly from ICN, I2 and AsF5 and characterized by chemical analysis, IR, Raman and 19F NMR data. A combined vibrational (IR, Raman) and theoretical study revealed the [ICNI]+ cation to be linear, the preference of the linear over the bent structure can easily be understood in terms of hyperconjugative interactions in the cationic species [natural bond order (NBO) analysis]. The molecular structure of the [ICNI]+ cation was computed semiempirically (Austin Model 1, AMI; reparameterization of AM1, PM3) and ab initio at the Hartree-Fock (HF/6-31G*) and correlated RMP2 (RMP, restricted Moller-Plesset) and RMP4(SDQ) levels of theory using quasi-relativistic pseudo-potentials (LANL2DZ) for the icdine atoms. The computed structural parameters at the highest level applied are: Cx, symmetry, RMP4(SDQ), d(I-C) = 2.001, d(C≡N) = 1.167, d/(N-I) = 2.021 A. The N-I bond dissociation enthalpy for [ICN-I]+ was calculated ab initio at the electron-correlated RMP2 level of theory as 207.4 kJ mol-1. The metathetical reaction of [ICNI]+[AsF6]- with CsN3 in SO2ClF afforded IN3, Cs+[AsF6]- and ICN.
